A three-dimensional network constructed from the assembly of 1,3-diaminopropane-copper(II) and tetracyanopalladate(II) moieties

被引：21
作者：
Legendre, Alexandre de Oliveira [1 ]
Mauro, Antonio Eduardo [1 ]
Rodrigues de Oliveira, Milene Aparecida [2 ]
do Prado Gambardella, Maria Teresa [2 ]
机构：
[1] Sao Paulo State Univ UNESP, Inst Quim Araraquara, BR-14800900 Araraquara, SP, Brazil
[2] Univ Sao Paulo, Inst Quim Sao Carlos, BR-13560970 Sao Carlos, SP, Brazil
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2008年 / 11卷 / 08期
基金：
巴西圣保罗研究基金会;
关键词：
copper(II); coordination polymers; tetracyanopalladate(II); 1,3-diaminopropane; supramolecular chemistry; hydrogen bonds;
D O I：
10.1016/j.inoche.2008.04.031
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The coordination polymer [Cu(Pd(CN)(4))(pn)](n) (pn = 1,3-diaminopropane) has been synthesized and characterized by elemental analysis, infrared spectroscopy and single-crystal X-ray diffraction. The crystal structure showed that three cyano groups of each [Pd(CN)(4)] unit bridge Cu(II) centers leading to the formation of a three-dimensional network. A series of bifurcated hydrogen bonds between the amino groups of the diamine and the nonbridging cyano groups of the cyanometallate result in the organization of suprarnolecular chains and rings along the polymer. (c) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码：896 / 898
页数：3
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