Unusual Formation of 21-Oxacorrole from 21-Oxaporphyrin Induced by Phosphoryl Chloride

被引：14

作者：

Ghosh, Avijit ^{[1
]}

Chatterjee, Tamal ^{[1
]}

Lee, Way-Zen ^{[2
]}

Ravikanth, Mangalampalli ^{[1
]}

机构：

[1] Indian Inst Technol, Bombay 400076, Maharashtra, India

[2] Natl Taiwan Normal Univ, Dept Chem, Instrumentat Ctr, Taipei 11677, Taiwan

来源：

ORGANIC LETTERS | 2013年 / 15卷 / 05期

关键词：

CORE-MODIFIED CORROLES; MODIFIED PORPHYRIN ENVIRONMENT; RING CONTRACTION; 1ST EXAMPLES; CONDENSATION; REACTIVITY;

D O I：

10.1021/ol303527v

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An unusual formation of 21-oxacorrole from 21-oxaporphyrin by concomitant elimination of a meso-aryl group and ring contraction is reported.

引用

页码：1040 / 1043

页数：4

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