The role of flow in green chemistry and engineering

被引:458
作者
Newman, Stephen G. [1 ]
Jensen, Klavs F. [1 ]
机构
[1] MIT, Dept Chem Engn, Cambridge, MA 02139 USA
基金
加拿大自然科学与工程研究理事会;
关键词
SUPERCRITICAL CARBON-DIOXIDE; CONTINUOUS PHOTOOXIDATION; PHOTOREDOX CATALYSIS; SELECTIVE OXIDATION; LIQUID-EXTRACTION; ORGANIC-SYNTHESIS; REACTION-KINETICS; SINGLET OXYGEN; HECK REACTION; HIGH-PRESSURE;
D O I
10.1039/c3gc40374b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Flow chemistry and continuous processing can offer many ways to make synthesis a more sustainable practice. These technologies help bridge the large gap between academic and industrial settings by often providing a more reproducible, scalable, safe and efficient option for performing chemical reactions. In this review, we use selected examples to demonstrate how continuous methods of synthesis can be greener than batch synthesis on a small and a large scale.
引用
收藏
页码:1456 / 1472
页数:17
相关论文
共 135 条
  • [91] A facile method for catalyst immobilisation on silica: nickel-catalysed Kumada reactions in mini-continuous flow and batch reactors
    Phan, NTS
    Brown, DH
    Styring, P
    [J]. GREEN CHEMISTRY, 2004, 6 (10) : 526 - 532
  • [92] The Continuous-Flow Synthesis of Carboxylic Acids using CO2 in a Tube-In-Tube Gas Permeable Membrane Reactor
    Polyzos, Anastasios
    O'Brien, Matthew
    Petersen, Trine P.
    Baxendale, Ian R.
    Ley, Steven V.
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2011, 50 (05) : 1190 - 1193
  • [93] Development of a continuous process for the industrial generation of diazomethane
    Proctor, LD
    Warr, AJ
    [J]. ORGANIC PROCESS RESEARCH & DEVELOPMENT, 2002, 6 (06) : 884 - 892
  • [94] Continuous Flow Organic Synthesis under High-Temperature/Pressure Conditions
    Razzaq, Tahseen
    Kappe, C. Oliver
    [J]. CHEMISTRY-AN ASIAN JOURNAL, 2010, 5 (06) : 1274 - 1289
  • [95] Rebsdat S., 2000, Ullmann's Encyclopedia of Industrial Chemistry, P495
  • [96] An Automated Continuous-Flow Platform for the Estimation of Multistep Reaction Kinetics
    Reizman, Brandon J.
    Jensen, Klavs F.
    [J]. ORGANIC PROCESS RESEARCH & DEVELOPMENT, 2012, 16 (11) : 1770 - 1782
  • [97] Development of an industrial multi-injection microreactor for fast and exothermic reactions - Part II
    Roberge, Dominique M.
    Bieler, Nikolaus
    Mathier, Meinrad
    Eyholzer, Markus
    Zimmermann, Bertin
    Barthe, Philippe
    Guermeur, Celine
    Lobet, Olivier
    Moreno, Maxime
    Woehl, Pierre
    [J]. CHEMICAL ENGINEERING & TECHNOLOGY, 2008, 31 (08) : 1155 - 1161
  • [98] Application of supercritical CO2 in lipid extraction - A review
    Sahena, F.
    Zaidul, I. S. M.
    Jinap, S.
    Karim, A. A.
    Abbas, K. A.
    Norulaini, N. A. N.
    Omar, A. K. M.
    [J]. JOURNAL OF FOOD ENGINEERING, 2009, 95 (02) : 240 - 253
  • [99] Sandee AJ, 2001, CHEM-EUR J, V7, P1202, DOI 10.1002/1521-3765(20010316)7:6<1202::AID-CHEM1202>3.3.CO
  • [100] 2-I