Palladium-Catalyzed Suzuki Coupling ofN-Acyloxazolidinones via Selective Cleavage of C-N Bonds

被引：10

作者：

Jian, Junsheng ^{[1
]}

He, Zhanyu ^{[1
]}

Zhang, Yuqi ^{[1
]}

Liu, Tingting ^{[1
]}

Liu, Lizhen ^{[1
]}

Wang, Zijia ^{[1
]}

Wang, Hui ^{[1
]}

Wang, Sanyong ^{[2
]}

Zeng, Zhuo ^{[1
]}

机构：

[1] South China Normal Univ, Coll Chem, Guangzhou 510006, Guangdong, Peoples R China

[2] Guangye L&P Food Ingredient Co Ltd, Guangzhou 510308, Guangdong, Peoples R China

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2020年 / 2020卷 / 27期

基金：

中国国家自然科学基金;

关键词：

Bond cleavage; N-Acyloxazolidiones; Palladium catalysis; Cross-coupling; Ketones; ELECTRONICALLY-ACTIVATED AMIDES; ACYL-TRANSFER REAGENTS; KETONE SYNTHESIS; CARBOXYLIC ANHYDRIDES; ARYLBORONIC ACIDS; GENERAL-METHOD; SECONDARY; ACCESS; ESTERS; NHC;

D O I：

10.1002/ejoc.202000575

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

By implementing a palladium-catalyzed Suzuki coupling reaction ofN-acyloxazolidinones with arylboronic acid, we herein report on the preparation of substituted diaryl ketones via selective cleavage of exocyclic C-N Bonds. The reaction was carried out under mild reaction conditions with excellent functional group compatibility in good yields (up to 93 %).

引用

页码：4176 / 4180

页数：5

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