Palladium-Catalyzed Suzuki Coupling ofN-Acyloxazolidinones via Selective Cleavage of C-N Bonds

被引：10
作者：
Jian, Junsheng [1 ]
He, Zhanyu [1 ]
Zhang, Yuqi [1 ]
Liu, Tingting [1 ]
Liu, Lizhen [1 ]
Wang, Zijia [1 ]
Wang, Hui [1 ]
Wang, Sanyong [2 ]
Zeng, Zhuo [1 ]
机构：
[1] South China Normal Univ, Coll Chem, Guangzhou 510006, Guangdong, Peoples R China
[2] Guangye L&P Food Ingredient Co Ltd, Guangzhou 510308, Guangdong, Peoples R China
来源：
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2020年 / 2020卷 / 27期
基金：
中国国家自然科学基金;
关键词：
Bond cleavage; N-Acyloxazolidiones; Palladium catalysis; Cross-coupling; Ketones; ELECTRONICALLY-ACTIVATED AMIDES; ACYL-TRANSFER REAGENTS; KETONE SYNTHESIS; CARBOXYLIC ANHYDRIDES; ARYLBORONIC ACIDS; GENERAL-METHOD; SECONDARY; ACCESS; ESTERS; NHC;
D O I：
10.1002/ejoc.202000575
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
By implementing a palladium-catalyzed Suzuki coupling reaction ofN-acyloxazolidinones with arylboronic acid, we herein report on the preparation of substituted diaryl ketones via selective cleavage of exocyclic C-N Bonds. The reaction was carried out under mild reaction conditions with excellent functional group compatibility in good yields (up to 93 %).
引用
收藏
页码：4176 / 4180
页数：5
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