Tritium release experiments on Li4SiO4 pebbles from TRINPC-I experiments: Effects of water adsorption and hydrogen gas

被引：12
作者：
Kang, Chunmei
Wang, Xiaolin
Xiao, Chengjian
He, Yuhui
Chen, Xiaojun
Liu, Jun
Wang, Heyi
Peng, Shuming
机构：
[1] Institute of Nuclear Physics and Chemistry, China Academy of Engineering Physics, 621900
[2] China Academy of Engineering Physics, 919-1
来源：
FUSION ENGINEERING AND DESIGN | 2013年 / 88卷 / 03期
关键词：
Li4SiO4; Tritium; Water adsorption effect; H-2; effect; POSTIRRADIATION EXAMINATIONS; LITHIUM ORTHOSILICATE; VAPORIZATION; SILICATES; CHEMISTRY; BEHAVIOR; DEFECTS; LIALO2;
D O I：
10.1016/j.fusengdes.2012.11.010
中图分类号：
TL [原子能技术]; O571 [原子核物理学];
学科分类号：
0827 ; 082701 ;
摘要：
Out-of-pile tritium release experiments under different water uptake contents and purge gas chemistry were performed on Li4SiO4. Water measurement was performed on samples under different experimental procedures. It was found that water was adsorbed on the sample during its transferring and storage process. A strong dependence of tritium release behavior on water uptake was determined. By doping H-2 in the sweep gas, the formation of water in orthosilicate was observed in addition to the isotope exchange reaction with H-2 gas. Thermal desorption peaks of the water formation reaction and H-2 isotope exchange reaction appeared at 668 degrees C and 463 degrees C, respectively, at ramping rate of 5 degrees C/min. (c) 2013 Published by Elsevier B.V.
引用
收藏
页码：113 / 117
页数：5
相关论文
共 21 条
[1]   Basic study of influence of radiation defects on tritium release processes from lithium silicates [J].
Abramenkovs, A ;
Tiliks, J ;
Kizane, G ;
Grishmanovs, V ;
Supe, A .
JOURNAL OF NUCLEAR MATERIALS, 1997, 248 :116-120
[2]  
Clemmer R.G., 1984, J NUCL MATER, V122&123, P890
[3]   Fabrication and characterization of Li4SiO4 ceramic pebbles by wet method [J].
Gao, Xiaoling ;
Chen, Xiaojun ;
Gu, Mei ;
Xiao, Chengjian ;
Peng, Shuming .
JOURNAL OF NUCLEAR MATERIALS, 2012, 424 (1-3) :210-215
[4]   Effect of surface water on tritium release behavior from Li4SiO4 [J].
Hanada, T. ;
Fukada, S. ;
Nishikawa, M. ;
Suematsu, K. ;
Yamashita, N. ;
Kanazawa, T. .
FUSION ENGINEERING AND DESIGN, 2010, 85 (7-9) :998-1001
[5]   Out-of-pile tritium release study on Li4SiO4 pebbles from TRINPC-I experiments [J].
Kang, Chunmei ;
Wang, Xiaolin ;
Xiao, Chengjian ;
Gao, Xiaoling ;
Gu, Mei ;
Liu, Jun ;
Wang, Heyi ;
Peng, Shuming ;
Chen, Xiaojun .
JOURNAL OF NUCLEAR MATERIALS, 2011, 412 (01) :62-65
[6]   Formation of water in lithium ceramics bed at hydrogen addition to purge gas [J].
Kawamura, Y ;
Nishikama, M ;
Shiraishi, T ;
Okuno, K .
JOURNAL OF NUCLEAR MATERIALS, 1996, 230 (03) :287-294
[7]  
Kurasawa T., 1986, DE88 007760, Patent No. 88007760
[8]   Tritium release kinetics of lithium silicates with irradiation defects [J].
Moritani, K ;
Magari, T ;
Moriyama, H .
FUSION ENGINEERING AND DESIGN, 1998, 39-40 :675-683
[9]   Effect of water vapor on tritium release from ceramic breeder material [J].
Munakata, K ;
Koga, A ;
Yokoyama, Y ;
Kanjo, S ;
Beloglazov, S ;
Ianovski, D ;
Takeishi, T ;
Penzhorn, RD ;
Kawamoto, K ;
Moriyama, H ;
Morimoto, Y ;
Akahori, S ;
Okuno, K .
FUSION ENGINEERING AND DESIGN, 2003, 69 (1-4) :27-31
[10]   Tritium release from lithium silicate pebbles produced from lithium hydroxide [J].
Munakata, Kenzo ;
Shinozaki, Takashi ;
Inoue, Keita ;
Kajii, Shunsaku ;
Shinozaki, Yohei ;
Knitter, Regina ;
Bekris, Nicolas ;
Fujii, Toshiyuki ;
Yamana, Hajimu ;
Okuno, Kenji .
FUSION ENGINEERING AND DESIGN, 2008, 83 (7-9) :1317-1320
123