Entangled Valence Electron-Hole Dynamics Revealed by Stimulated Attosecond X-ray Raman Scattering

被引：25
作者：
Healion, Daniel [1 ]
Zhang, Yu [1 ]
Biggs, Jason D. [1 ]
Govind, Niranjan [2 ]
Mukamel, Shaul [1 ]
机构：
[1] Univ Calif Irvine, Dept Chem, Irvine, CA 92697 USA
[2] Pacific NW Natl Lab, William R Wiley Environm Mol Sci Lab, Richland, WA 99352 USA
来源：
JOURNAL OF PHYSICAL CHEMISTRY LETTERS | 2012年 / 3卷 / 17期
基金：
美国国家科学基金会; 美国国家卫生研究院;
关键词：
DENSITY-FUNCTIONAL THEORY; SPECTROSCOPY;
D O I：
10.1021/jz300981w
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
We show that broadband X-ray pulses can create wavepackets of valence electrons and holes localized in the vicinity of a selected atom (nitrogen, oxygen, or sulfur in cysteine) by stimulated resonant Raman scattering. The subsequent dynamics reveals highly correlated motions of entangled electron and hole quasiparticles. This information goes beyond the time-dependent total charge density derived from X-ray diffraction.
引用
收藏
页码：2326 / 2331
页数：6
相关论文
共 50 条
  • [41] Observation of Seeded Mn Kβ Stimulated X-Ray Emission Using Two-Color X-Ray Free-Electron Laser Pulses
    Kroll, Thomas
    Weninger, Clemens
    Fuller, Franklin D.
    Guetg, Marc W.
    Benediktovitch, Andrei
    Zhang, Yu
    Marinelli, Agostino
    Alonso-Mori, Roberto
    Aquila, Andy
    Liang, Mengning
    Koglin, Jason E.
    Koralek, Jake
    Sokaras, Dimosthenis
    Zhu, Diling
    Kern, Jan
    Yano, Junko
    Yachandra, Vittal K.
    Rohringer, Nina
    Lutman, Alberto
    Bergmann, Uwe
    PHYSICAL REVIEW LETTERS, 2020, 125 (03)
  • [42] Optimizing the slicing pattern of stress-relief crystal analyzers for X-ray Raman scattering
    Diao, Qianshun
    Zhang, Yujun
    Jin, Shuoxue
    He, Shangming
    Zeng, Jianrong
    Bian, Fenggang
    Yang, Junliang
    Hong, Zhen
    Lian, Hongkai
    Gan, Xiaolong
    Zhang, Han
    Li, Ming
    Liu, Peng
    Chen, Dongliang
    Guo, Zhiying
    Xu, Wei
    JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2023, 56 : 1505 - 1511
  • [43] Oxide Nanolayers in Stratified Samples Studied by X-Ray Resonant Raman Scattering at Grazing Incidence
    Jose Leani, Juan
    Jorge Sanchez, Hector
    Perez, Carlos Alberto
    JOURNAL OF SPECTROSCOPY, 2015, 2015
  • [44] High-pressure Raman scattering and x-ray diffraction studies of the supercritical fluid of hydrogen
    Akahama, Yuichi
    Miyamoto, Ryosuke
    Nakano, Satoshi
    Kawaguchi, Saori
    Hirao, Naohisa
    Ohishi, Yasuo
    JOURNAL OF APPLIED PHYSICS, 2020, 128 (13)
  • [45] Structure of β-lactoglobulin microgels formed during heating as revealed by small-angle X-ray scattering and light scattering
    Moitzi, Christian
    Donato, Laurence
    Schmitt, Christophe
    Bovetto, Lionel
    Gillies, Graeme
    Stradner, Anna
    FOOD HYDROCOLLOIDS, 2011, 25 (07) : 1766 - 1774
  • [46] Raman scattering and X-ray diffraction investigations of sol-gel derived SBN powders
    Ho, MMT
    Mak, CL
    Wong, KH
    JOURNAL OF THE EUROPEAN CERAMIC SOCIETY, 1999, 19 (6-7) : 1115 - 1118
  • [47] Simulation of ultrafast excited-state dynamics and elastic x-ray scattering by quantum wavepacket dynamics
    Papai, Matyas
    Rozgonyi, Tamas
    Penfold, Thomas J.
    Nielsen, Martin M.
    Moller, Klaus B.
    JOURNAL OF CHEMICAL PHYSICS, 2019, 151 (10)
  • [48] Metal-Ligand Covalency in the Valence Excited States of Metal Dithiolenes Revealed by S 1s3p Resonant Inelastic X-ray Scattering
    Larsen, Christopher B.
    Ledbetter, Kathryn
    Nascimento, Daniel R.
    Biasin, Elisa
    Qureshi, Muhammad
    Nowak, Stanislaw H.
    Sokaras, Dimosthenis
    Govind, Niranjan
    Cordones, Amy A.
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2024, 146 (41) : 28561 - 28571
  • [49] Electronic structure of dense solid oxygen from insulator to metal investigated with X-ray Raman scattering
    Fukui, Hiroshi
    Le The Anh
    Wada, Masahiro
    Hiraoka, Nozomu
    Iitaka, Toshiaki
    Hirao, Naohisa
    Akahama, Yuichi
    Irifune, Tetsuo
    PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 2019, 116 (43) : 21385 - 21391
  • [50] Exploring the fundamental effects of deposition time on the microstructure of graphene nanoflakes by Raman scattering and X-ray diffraction
    Soin, Navneet
    Roy, Susanta Sinha
    O'Kane, Christopher
    McLaughlin, James A. D.
    Lim, Teck H.
    Hetherington, Crispin J. D.
    CRYSTENGCOMM, 2011, 13 (01): : 312 - 318
12345