Microstructure and thermal conductivity of Cu/diamond composites with Ti-coated diamond particles produced by gas pressure infiltration

被引:107
作者
Li, Jianwei [1 ]
Zhang, Hailong [1 ]
Zhang, Yang [1 ]
Che, Zifan [1 ]
Wang, Xitao [1 ]
机构
[1] Univ Sci & Technol Beijing, State Key Lab Adv Met & Mat, Beijing 100083, Peoples R China
基金
中国国家自然科学基金;
关键词
Metal matrix composites; Liquid-solid reactions; Heat conduction; Auger electron spectroscopy; CU-ZR/DIAMOND COMPOSITES; INTERMEDIATE LAYERS; COPPER; EXPANSION; PRETREATMENT; RESISTANCE; POWDER; MATRIX; SPS; CR;
D O I
10.1016/j.jallcom.2015.06.062
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
As an attractive thermal management material, diamond particles reinforced Cu matrix (Cu/diamond) composites generally exhibit thermal conductivities lower than expected. To exploit the potential of heat conduction, a combination of Ti coating on diamond particles and gas pressure infiltration was used to prepare Cu/diamond(Ti) composites. A high thermal conductivity of 716 W/mK and a low coefficient of thermal expansion of 5.8 ppm/K at 323 K were obtained in the composites. Auger electron spectroscopy (AES) characterization shows that a TiC layer was formed between Cu matrix and diamond reinforcement, which is responsible for the enhancement of thermal conductivity. The results suggest that Ti coating can significantly promote interface bonding between Cu and diamond and gas pressure infiltration is an effective method to produce Cu/diamond composites. (C) 2015 Elsevier B.V. All rights reserved.
引用
收藏
页码:941 / 946
页数:6
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