Eutectic salts promote green synthesis of bis(indolyl) methanes

被引：70
作者：
Azizi, Najmadin [1 ]
Manocheri, Zohreh [2 ]
机构：
[1] Chem & Chem Engn Res Ctr Iran, Tehran, Iran
[2] Islamic Azad Univ, Dept Chem, Shahr E Rey Branch, Tehran, Iran
来源：
RESEARCH ON CHEMICAL INTERMEDIATES | 2012年 / 38卷 / 07期
关键词：
Bis(indolyl) methanes; Carbonyl compounds; Deep eutectic solvent; Green chemistry; Indole; ONE-POT SYNTHESIS; EFFICIENT SYNTHESIS; CARBONYL-COMPOUNDS; IONIC LIQUIDS; CATALYST; INDOLES; MILD;
D O I：
10.1007/s11164-011-0479-4
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A convenient and rapid method for the electrophilic substitution reaction of indoles with carbonyl compounds has been developed by using deep eutectic solvent as green and reusable catalysts to afford the corresponding bis(indolyl) methanes in excellent yields at room temperature under mild reaction conditions.
引用
收藏
页码：1495 / 1500
页数：6
相关论文
共 32 条
[1]  
Abbott A.P., 2003, CHEM COMMUN, V70-71, P22
[2]   Glycerol eutectics as sustainable solvent systems [J].
Abbott, Andrew P. ;
Harris, Robert C. ;
Ryder, Karl S. ;
D'Agostino, Carmine ;
Gladden, Lynn F. ;
Mantle, Mick D. .
GREEN CHEMISTRY, 2011, 13 (01) :82-90
[3]   One-pot synthesis of dithiocarbamates accelerated in water [J].
Azizi, N ;
Aryanasab, F ;
Torkiyan, L ;
Ziyaei, A ;
Saidi, MR .
JOURNAL OF ORGANIC CHEMISTRY, 2006, 71 (09) :3634-3635
[4]   Highly efficient one-pot three-component Mannich reaction in water catalyzed by heteropoly acids [J].
Azizi, N ;
Torkiyan, L ;
Saidi, MR .
ORGANIC LETTERS, 2006, 8 (10) :2079-2082
[5]   Highly chemoselective addition of amines to epoxides in water [J].
Azizi, N ;
Saidi, MR .
ORGANIC LETTERS, 2005, 7 (17) :3649-3651
[6]   Straightforward and highly efficient catalyst-free one-pot synthesis of dithiocarbamates under solvent-free conditions [J].
Azizi, Najmedin ;
Aryanasab, Fezzeh ;
Saidi, Mohammad R. .
ORGANIC LETTERS, 2006, 8 (23) :5275-5277
[7]   Toward a practical and waste-free synthesis of thioureas in water [J].
Azizi, Najmedin ;
Khajeh-Amiri, Alireza ;
Ghafuri, Hossein ;
Bolourtchian, Mohammad .
MOLECULAR DIVERSITY, 2011, 15 (01) :157-161
[8]   Highly efficient synthesis of bis(indolyl)methanes in water [J].
Azizi, Najmodin ;
Torkian, Lalleh ;
Saidi, Mohammad R. .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2007, 275 (1-2) :109-112
[9]   Molecular iodine-catalyzed efficient and highly rapid synthesis of bis(indolyl)methanes under mild conditions [J].
Bandgar, BP ;
Shaikh, KA .
TETRAHEDRON LETTERS, 2003, 44 (09) :1959-1961
[10]   Solvent-free indoles addition to carbonyl compounds promoted by CeCl3•7H2O-NaI-SiO2:: An efficient method for the synthesis of streptindole [J].
Bartoli, G ;
Bosco, M ;
Foglia, G ;
Giuliani, A ;
Marcantoni, E ;
Sambri, L .
SYNTHESIS-STUTTGART, 2004, (06) :895-900
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