Multifunctional Benzoquinone Additive for Efficient and Stable Planar Perovskite Solar Cells

被引：143

作者：

Qin, Chuanjiang ^{[1
,2
]}

Matsushima, Toshinori ^{[1
,2
]}

Fujihara, Takashi ^{[3
]}

Adachi, Chihaya ^{[1
,2
]}

机构：

[1] Kyushu Univ, Ctr Organ Photon & Elect Res OPERA, Nishi Ku, 744 Motooka, Fukuoka 8190395, Japan

[2] Japan Sci & Technol Agcy JST, ERATO, Adachi Mol Exciton Engn Project, Nishi Ku, 744 Motooka, Fukuoka 8190395, Japan

[3] Informat Technol & Nanotechnol ISIT, Innovat Organ Device Lab, Inst Syst, Nishi Ku, 744 Motooka, Fukuoka 8190395, Japan

来源：

ADVANCED MATERIALS | 2017年 / 29卷 / 04期

关键词：

LEAD; PERFORMANCE; HYSTERESIS; STABILITY; STATES; TIO2;

D O I：

10.1002/adma.201603808

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Device stability of planar perovskite solar cells is improved by virtue of multifunctional BQ additive. The morphology and crystal quality of the perovskite films are improved because BQ slows the rate of perovskite crystal formation. Electron transfer from perovskite to BQ reduces charge-recombination losses, and the oxidizing ability of BQ effectively suppresses the formation of metallic lead and improves device lifetime.

引用

页数：8

共 42 条

[21] Overcoming ultraviolet light instability of sensitized TiO2 with meso-superstructured organometal tri-halide perovskite solar cells [J].

Leijtens, Tomas ;

Eperon, Giles E. ;

Pathak, Sandeep ;

Abate, Antonio ;

Lee, Michael M. ;

Snaith, Henry J. .

NATURE COMMUNICATIONS, 2013, 4

[22]

Li X, 2015, NAT CHEM, V7, P703, DOI [10.1038/NCHEM.2324, 10.1038/nchem.2324]

[23]

Lin QQ, 2015, NAT PHOTONICS, V9, P106, DOI [10.1038/nphoton.2014.284, 10.1038/NPHOTON.2014.284]

[24] Perovskite solar cells with a planar heterojunction structure prepared using room-temperature solution processing techniques [J].

Liu, Dianyi ;

Kelly, Timothy L. .

NATURE PHOTONICS, 2014, 8 (02) :133-138

[25] Efficient planar heterojunction perovskite solar cells by vapour deposition [J].

Liu, Mingzhen ;

Johnston, Michael B. ;

Snaith, Henry J. .

NATURE, 2013, 501 (7467) :395-+

[26] Methylammonium Lead Iodide for Efficient X-ray Energy Conversion [J].

Nafradi, Balint ;

Nafradi, Gabor ;

Forro, Laszlo ;

Horvath, Endre .

JOURNAL OF PHYSICAL CHEMISTRY C, 2015, 119 (45) :25204-25208

[27]

Patai S., 1988, CHEM QUINONOID COMPO

[28] Degradation Mechanisms of Solution-Processed Planar Perovskite Solar Cells: Thermally Stimulated Current Measurement for Analysis of Carrier Traps [J].

Qin, Chuanjiang ;

Matsushima, Toshinori ;

Fujihara, Takashi ;

Potscavage, William J., Jr. ;

Adachi, Chihaya .

ADVANCED MATERIALS, 2016, 28 (03) :466-471

[29] Influence of Air Annealing on High Efficiency Planar Structure Perovskite Solar Cells [J].

Raga, Sonia R. ;

Jung, Min-Cherl ;

Lee, Michael V. ;

Leyden, Matthew R. ;

Kato, Yuichi ;

Qi, Yabing .

CHEMISTRY OF MATERIALS, 2015, 27 (05) :1597-1603

[30] Procedures and Practices for Evaluating Thin-Film Solar Cell Stability [J].

Roesch, Roland ;

Faber, Tobias ;

von Hauff, Elizabeth ;

Brown, Thomas M. ;

Lira-Cantu, Monica ;

Hoppe, Harald .

ADVANCED ENERGY MATERIALS, 2015, 5 (20)

← 1 2 3 4 5 →