Morphotropic phase boundary and electric properties in (1-x)Bi0.5Na0.5TiO3-xBaSnO3 lead-free piezoelectric ceramics

被引:9
作者
Jiao, Long [1 ]
Guo, Fei-Fei [2 ]
Wang, Jin-Feng [1 ]
Gu, Zheng-Bin [1 ]
Zhang, Shan-Tao [1 ]
Yang, Bin [2 ]
机构
[1] Nanjing Univ, Dept Mat Sci & Engn, Natl Lab Solid State Microstruct, Nanjing 210093, Jiangsu, Peoples R China
[2] Harbin Inst Technol, Ctr Condensed Matter Sci & Technol, Harbin 150001, Peoples R China
基金
国家教育部博士点专项基金资助;
关键词
FREE PIEZOCERAMICS;
D O I
10.1007/s10854-013-1364-2
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
Lead-free piezoceramics of (1 - x)Bi0.5Na0.5TiO3-xBaSnO(3) (BNT-BS, x = 0, 0.02, 0.03, 0.04, 0.06, 0.09 and 0.12) have been synthesized and investigated. A rhombohedral-tetragonal morphotropic phase boundary (MPB) exists near x = 0.03. The MPB composition shows improved electrical properties: the saturated polarization, remnant polarization, coercive field, piezoelectric coefficient, planar electromechanical coupling factor, and unipolar strain are 35.8, 28.5 mu C/cm(2), and 4.5 kV/mm, 93 pC/N, 0.19, and 0.18 %, respectively. It is also found the introduction of BS can significantly enhance dielectric property. The structural and electrical properties are discussed by comparing with other BNT-based piezoceramics.
引用
收藏
页码:4080 / 4084
页数:5
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