Environmentally friendly superabsorbent fibers based on electrospun cellulose nanofibers extracted from wheat straw

被引:48
作者
Petroudy, Seyed Rahman Djafari [1 ]
Kahagh, Sajad Arjmand [1 ]
Vatankhah, Elham [2 ]
机构
[1] Shahid Beheshti Univ, Fac New Technol Engn, Biorefinery Engn Dept, Cellulose Nanotechnol Lab, Zirab Campus, Tehran, Iran
[2] Shahid Beheshti Univ, Fac New Technol Engn, Biosyst Engn Dept, Zirab Campus, Tehran, Iran
基金
美国国家科学基金会;
关键词
Cellulose nanofibers; Electrospinning; Superabsorbent fibers; Wheat straw; TRIFLUOROACETIC-ACID; STEAM EXPLOSION; HYDROGELS; HYDROLYSIS; COMPOSITE; OXIDATION; SOLVENTS; XYLAN;
D O I
10.1016/j.carbpol.2020.117087
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
Superabsorbent polymers currently used in health and agricultural sectors are based on petroleum-based materials which led to serious concerns in the society. Here, superabsorbent fibers (SAFs) based on electrospun cellulose nanofibers (ECNFs) were prepared. Firstly, cellulose was removed from wheat straw, pre-treated with the TEMPO-mediated oxidation and subsequently dissolved into Trifluoroacetic acid for production of ECNFs through the electrospinning approach. The maximum swelling ratios of 225 g/g and 208 g/g in distilled water and 0.9 wt% NaCl solution were measured for ESAFs composed of oxidized ECNFs containing 15 % poly (sodium acrylate), respectively. The ESAFs were characterized using Fourier transform infrared spectroscopy and field emission scanning electron microscopy analysis. The FESEM showed that ESAFs formed high strength three-dimensional architecture networks. Also, the results showed that the ionic sensitivity of this ECNFs were low. The prepared ESAFs are attractive renewable alternatives for different applications, contributing to a reduction of plastic microspheres.
引用
收藏
页数:13
相关论文
共 48 条
[1]   Synthesis and swelling behaviors of sodium carboxymethyl cellulose-g-poly(AA-co-AM-co-AMPS)/MMT superabsorbent hydrogel [J].
Bao, Yan ;
Ma, Jianzhong ;
Li, Na .
CARBOHYDRATE POLYMERS, 2011, 84 (01) :76-82
[2]   Cellulose-based hydrogels for personal care products [J].
Bashari, Azadeh ;
Shirvan, Anahita Rouhani ;
Shakeri, Mina .
POLYMERS FOR ADVANCED TECHNOLOGIES, 2018, 29 (12) :2853-2867
[3]   Fractionation of five technical lignins by selective extraction in green solvents and characterisation of isolated fractions [J].
Boeriu, Carmen G. ;
Fitigau, Firuta I. ;
Gosselink, Richard J. A. ;
Frissen, August E. ;
Stoutjesdijk, Jan ;
Peter, Francisc .
INDUSTRIAL CROPS AND PRODUCTS, 2014, 62 :481-490
[4]   Multiresponsive Hydrogels Based on Xylan-Type Hemicelluloses and Photoisomerized Azobenzene Copolymer as Drug Delivery Carrier [J].
Cao, Xuefei ;
Peng, Xinwen ;
Zhong, Linxin ;
Sun, Runcang .
JOURNAL OF AGRICULTURAL AND FOOD CHEMISTRY, 2014, 62 (41) :10000-10007
[5]   Fabrication of superabsorbent nanofibers based on sodium polyacrylate/poly(vinyl alcohol) and their water absorption characteristics [J].
Choi, Sejin ;
Kim, Hye Ri ;
Kim, Han Seong .
POLYMER INTERNATIONAL, 2019, 68 (04) :764-771
[6]   Influence of alkali treatment on the fine structure and morphology of bamboo fibers [J].
Das, Mahuya ;
Chakraborty, Debabrata .
JOURNAL OF APPLIED POLYMER SCIENCE, 2006, 102 (05) :5050-5056
[7]   HYDROLYSIS OF WHEAT STRAW HEMICELLULOSE WITH TRIFLUOROACETIC-ACID - FERMENTATION OF XYLOSE WITH PACHYSOLEN-TANNOPHILUS [J].
FANTA, GF ;
ABBOTT, TP ;
HERMAN, AI ;
BURR, RC ;
DOANE, WM .
BIOTECHNOLOGY AND BIOENGINEERING, 1984, 26 (09) :1122-1125
[8]   On the Effect of Chemical Composition on the Desorption of Superabsorbent Hydrogels in Contact with a Porous Cementitious Material [J].
Farzanian, Khashayar ;
Ghahremaninezhad, Ali .
GELS, 2018, 4 (03)
[9]   Beaded nanofibers formed during electrospinning [J].
Fong, H ;
Chun, I ;
Reneker, DH .
POLYMER, 1999, 40 (16) :4585-4592
[10]   Nanocrystalline cellulose applied simultaneously as the gate dielectric and the substrate in flexible field effect transistors [J].
Gaspar, D. ;
Fernandes, S. N. ;
de Oliveira, A. G. ;
Fernandes, J. G. ;
Grey, P. ;
Pontes, R. V. ;
Pereira, L. ;
Martins, R. ;
Godinho, M. H. ;
Fortunato, E. .
NANOTECHNOLOGY, 2014, 25 (09)