共 48 条
Environmentally friendly superabsorbent fibers based on electrospun cellulose nanofibers extracted from wheat straw
被引:48
作者:
Petroudy, Seyed Rahman Djafari
[1
]
Kahagh, Sajad Arjmand
[1
]
Vatankhah, Elham
[2
]
机构:
[1] Shahid Beheshti Univ, Fac New Technol Engn, Biorefinery Engn Dept, Cellulose Nanotechnol Lab, Zirab Campus, Tehran, Iran
[2] Shahid Beheshti Univ, Fac New Technol Engn, Biosyst Engn Dept, Zirab Campus, Tehran, Iran
基金:
美国国家科学基金会;
关键词:
Cellulose nanofibers;
Electrospinning;
Superabsorbent fibers;
Wheat straw;
TRIFLUOROACETIC-ACID;
STEAM EXPLOSION;
HYDROGELS;
HYDROLYSIS;
COMPOSITE;
OXIDATION;
SOLVENTS;
XYLAN;
D O I:
10.1016/j.carbpol.2020.117087
中图分类号:
O69 [应用化学];
学科分类号:
081704 ;
摘要:
Superabsorbent polymers currently used in health and agricultural sectors are based on petroleum-based materials which led to serious concerns in the society. Here, superabsorbent fibers (SAFs) based on electrospun cellulose nanofibers (ECNFs) were prepared. Firstly, cellulose was removed from wheat straw, pre-treated with the TEMPO-mediated oxidation and subsequently dissolved into Trifluoroacetic acid for production of ECNFs through the electrospinning approach. The maximum swelling ratios of 225 g/g and 208 g/g in distilled water and 0.9 wt% NaCl solution were measured for ESAFs composed of oxidized ECNFs containing 15 % poly (sodium acrylate), respectively. The ESAFs were characterized using Fourier transform infrared spectroscopy and field emission scanning electron microscopy analysis. The FESEM showed that ESAFs formed high strength three-dimensional architecture networks. Also, the results showed that the ionic sensitivity of this ECNFs were low. The prepared ESAFs are attractive renewable alternatives for different applications, contributing to a reduction of plastic microspheres.
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页数:13
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