Synthesis of novel electrochemfluminescent polyamine dendrimers functionalized with polypyridyl Ru(II) complexes and their electrochemical properties

被引：0
作者：
Lee, DN
Park, HS
Kim, EH
Jun, YM
Lee, JY
Lee, WY [1 ]
Kim, BH
机构：
[1] Kwangwoon Univ, Dept Chem, Seoul 139701, South Korea
[2] Yonsei Univ, Dept Chem, Seoul 120749, South Korea
[3] Yonsei Univ, Ctr Bioact Mol Hybrids, Seoul 120749, South Korea
来源：
BULLETIN OF THE KOREAN CHEMICAL SOCIETY | 2006年 / 27卷 / 01期
关键词：
electrochemiluminescence; ruthenium(II) complexes; polyamine dendrimer;
D O I：
暂无
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Polyamine dendrimers functionalized with electrochemiluminescent (ECL) polypyridyl Ru(II) complexes, dend-[CO-(CH2)(3)-mbpy(.)Ru(L)(2)](3)(PF6)(6) (dend: N(CH2CH2NH)(3)-, L: bpy, o-phen, phen-Cl, DTDP), were synthesized through the complexation of dendritic polypyridyl ligands to Ru(II) complexes. Their electrochemical redox potentials, photoluminescence (PL), and relative ECL intensities were studied. The ECL emissions produced by the reaction between the electro-oxidized Ru3+ species of polyamine dendrimers and tripropylamine as a coreactant were measured in a static system with potential cycles between 0.8 and 1.3 V or through flow injection analysis with a potential of +1.3 V, and were compared to that of [Ru(o-phen)(3)](PF6)(2). Dend-[CO-(CH2)(3)-mbpy-Ru(bpy)(2)](3)(PF6)(6) showed an ECL intensity that was two-fold greater than that of the reference complex [Ru(o-phen)(3)](PF6)(2).
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页码：99 / 105
页数：7
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