Synthesis of η2-allene complexes by the reaction of a η1-vinylidene tungsten complex with diazoalkanes

被引：7

作者：

Ipaktschi, J ^{[1
]}

Rooshenas, P ^{[1
]}

Dülmer, A ^{[1
]}

机构：

[1] Univ Giessen, Inst Organ Chem, D-35392 Giessen, Germany

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2006年 / 07期

关键词：

tungsten; vinylidene ligands; allene ligands; diazoalkanes;

D O I：

10.1002/ejic.200500958

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of the eta(1)-vinylidene complex Cp(CO)(NO)W=C=CH2 (5) with diazomethane, to give complex 8, as well as with ethyl diazoacetate, to give complexes 10 and 11, is described. The crystal structures of these complexes are reported. ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2006)

引用

页码：1456 / 1459

页数：4

共 34 条

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