Performance measurements of a single cell flowing electrolyte-direct methanol fuel cell (FE-DMFC)

被引:17
作者
Sabet-Sharghi, Nasim [1 ]
Cruickshank, Cynthia Ann [1 ]
Matida, Edgar [1 ]
Hamdullahpur, Feridun [2 ]
机构
[1] Carleton Univ, Mech & Aerosp Eng Dept, Ottawa, ON K1S 5B6, Canada
[2] Univ Waterloo, Dept Mech Engn, Waterloo, ON N2L 3G1, Canada
基金
加拿大自然科学与工程研究理事会;
关键词
Flowing electrolyte; Direct methanol fuel cell; Methanol crossover; Nafion; MEMBRANES; CROSSOVER;
D O I
10.1016/j.jpowsour.2012.11.147
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The performance of a single cell flowing electrolyte-direct methanol fuel cell (FE-DMFC) was experimentally studied and its performance was compared to a regular DMFC. The active area of the fuel cell was approximately 25 cm(2). Serpentine channels were used for both the methanol and air flows. Two combinations of Nafion (R) polymer electrolyte membranes (PEMs) were used in the MEAs. These were NR-212/N-117 (Type 1) and NR-212/NR-212 (Type 2). For this study, diluted sulphuric acid was used as the electrolyte, which flows through a channel made of a polyethylene porous material. The flowing electrolyte conditions (e.g., flow rate, channel thickness and sulphuric acid concentration), the methanol concentration, and the fuel cell temperatures were varied to study how these parameters affect the overall performance of the FE-DMFC. Type 1 MEA used in conjunction with 2 M methanol produced the highest current density. The power density decreased when the thickness of the flowing electrolyte channel was increased, and the performance of the fuel cell increased when the temperature of the fuel cell was increased, as expected. The results show that the performance of the present FE-DMFC was similar to a DMFC using the same active area and a single MEA (Nafion (R) N-117). (C) 2012 Elsevier B.V. All rights reserved.
引用
收藏
页码:194 / 200
页数:7
相关论文
共 23 条
[1]   Membraneless laminar flow-based micro fuel cells operating in alkaline, acidic, and acidic/alkaline media [J].
Choban, ER ;
Spendelow, JS ;
Gancs, L ;
Wieckowski, A ;
Kenis, PJA .
ELECTROCHIMICA ACTA, 2005, 50 (27) :5390-5398
[2]  
Darling H.E., 1964, J CHEM ENG DATA, V9, P421, DOI [10.1021/je60022a041, DOI 10.1021/JE60022A041]
[3]  
DeLuca N., 2008, THESIS DREXEL U
[4]  
Dillon R., 2005, FUEL CELLS COMPENDIU
[5]   Nanoporous separator and low fuel concentration to minimize crossover in direct methanol laminar flow fuel cells [J].
Hollinger, A. S. ;
Maloney, R. J. ;
Jayashree, R. S. ;
Natarajan, D. ;
Markoski, L. J. ;
Kenis, P. J. A. .
JOURNAL OF POWER SOURCES, 2010, 195 (11) :3523-3528
[6]   Microfluidic hydrogen fuel cell with a liquid electrolyte [J].
Jayashree, Ranga S. ;
Mitchell, Michael ;
Natarajan, Dilip ;
Markoski, Larry J. ;
Kenis, Paul J. A. .
LANGMUIR, 2007, 23 (13) :6871-6874
[7]   On the performance of membraneless laminar flow-based fuel cells [J].
Jayashree, Ranga S. ;
Yoon, Seong Kee ;
Brushett, Fikile R. ;
Lopez-Montesinos, Pedro O. ;
Natarajan, Dilip ;
Markoski, Larry J. ;
Kenis, Paul J. A. .
JOURNAL OF POWER SOURCES, 2010, 195 (11) :3569-3578
[8]  
Kauranen PS, 1996, J APPL ELECTROCHEM, V26, P909
[9]   A parametric study of methanol crossover in a flowing electrolyte-direct methanol fuel cell [J].
Kjeang, E ;
Goldak, J ;
Golriz, MR ;
Gu, J ;
James, D ;
Kordesch, K .
JOURNAL OF POWER SOURCES, 2006, 153 (01) :89-99
[10]   Direct methanol-air fuel cells with membranes plus circulating electrolyte [J].
Kordesch, K ;
Hacker, V ;
Bachhiesl, U .
JOURNAL OF POWER SOURCES, 2001, 96 (01) :200-203