Helium-hydrogen immiscibility at high pressures

被引:7
作者
Wang, Yu [1 ,2 ,3 ]
Zhang, Xiao [1 ,2 ,3 ]
Jiang, Shuqing [1 ,2 ]
Geballe, Zachary M. [4 ]
Pakornchote, Teerachote [4 ,5 ]
Somayazulu, Maddury [4 ]
Prakapenka, Vitali B. [6 ]
Greenberg, Eran [6 ]
Goncharov, Alexander F. [1 ,2 ,3 ,4 ]
机构
[1] Chinese Acad Sci, Inst Solid State Phys, Key Lab Mat Phys, Hefei 230031, Anhui, Peoples R China
[2] Chinese Acad Sci, Inst Solid State Phys, Ctr Energy Matter Extreme Environm, Hefei 230031, Anhui, Peoples R China
[3] Univ Sci & Technol China, Hefei 230026, Anhui, Peoples R China
[4] Carnegie Inst Sci, Geophys Lab, 5251 Broad Branch Rd, Washington, DC 20015 USA
[5] Chulalongkorn Univ, Dept Phys, Bangkok 10330, Thailand
[6] Univ Chicago, Ctr Adv Radiat Sources, Chicago, IL 60637 USA
基金
美国国家科学基金会; 中国国家自然科学基金;
关键词
X-RAY-DIFFRACTION; EQUATION-OF-STATE; BINARY PHASE-DIAGRAM; HIGH-TEMPERATURE; INTERIORS; MIXTURES; COMPOUND; JUPITER; SODIUM; POLYHYDRIDES;
D O I
10.1063/1.5086270
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Hydrogen and helium are the most abundant elements in the universe, and they constitute the interiors of gas giant planets. Thus, their equations of states, phase, chemical state, and chemical reactivity at extreme conditions are of great interest. Applying Raman spectroscopy, visual observation, and synchrotron X-ray diffraction in diamond anvil cells, we performed experiments on H-2-He 1:1 and D-2-He 1:10 compressed gas mixtures up to 100 GPa at 300 K. By comparing with the available data on pure bulk materials, we find no sign of miscibility, chemical reactivity, and new compound formation. This result establishes a new baseline for future investigations of miscibility in the He-H-2 system at extreme P-T conditions. Published under license by AIP Publishing.
引用
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页数:6
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