Electrochemical characterization of self-assembled monolayer of a novel manganese tetrabenzylthio-substituted phthalocyanine and its use in nitrite oxidation

被引：15
|
作者：
Matemadombo, Fungisai [1 ,2 ]
Griveau, Sophie [1 ]
Bedioui, Fethi [1 ]
Nyokong, Tebello [2 ]
机构：
[1] Ecole Natl Super Chim Paris, INSERM 640, CNRS 8151, Unite Pharmacol Chim & Genet, F-75231 Paris, France
[2] Rhodes Univ, Dept Chem, ZA-6140 Grahamstown, South Africa
来源：
ELECTROANALYSIS | 2008年 / 20卷 / 17期
基金：
美国安德鲁·梅隆基金会; 新加坡国家研究基金会;
关键词：
manganese phthalocyanine; cyclic voltammetry; self-assembled monolayer; impedance spectroscopy; nitrite oxidation; electrochemical scanning microscopy;
D O I：
10.1002/elan.200804269
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
Manganese phthalocyanine MnPc(Sph)(4) has been synthesized and used to form self assembled monolayers on gold electrodes. The well packed SAM monolayer was characterized by analyzing the blocking of a number of Faradic processes by cyclic voltammetry, evaluating the electrical characteristics of the modified electrode by electrochemical impedance and imaging the modified surface by electrochemical scanning microscopy. Finally, MnPc(SPh)(4)-SAM modified electrode displayed an electrocatalytic behavior toward the oxidation of nitrite.
引用
收藏
页码：1863 / 1872
页数：10
相关论文
共 44 条
  • [31] Electrochemical characterization of in situ functionalized gold cysteamine self-assembled monolayer with 4-formylphenylboronic acid for detection of dopamine
    Shervedani, Reza Karimi
    Bagherzadeh, Mojtaba
    ELECTROANALYSIS, 2008, 20 (05) : 550 - 557
  • [32] Fabrication and characterization of a new self-assembled monolayer of fullerene dicarboxylic acid derivative and its photoelectric conversion property
    Wei, TX
    Zhai, J
    Ge, JH
    Gan, LB
    Huang, CH
    Luo, GB
    Ying, LM
    Liu, TT
    Zhao, XS
    JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2000, 222 (02) : 262 - 264
  • [33] Synthesis, electrochemical characterization of tetra- and octa-substituted dodecyl-mercapto tin phthalocyanines in solution and as self-assembled monolayers
    Khene, Samson
    Geraldo, Daniela A.
    Togo, Chamunorwa A.
    Limson, Janice
    Nyokong, Tebello
    ELECTROCHIMICA ACTA, 2008, 54 (02) : 183 - 191
  • [34] Electrochemical characterization of self-assembled monolayers on gold substrates derived from thermal decomposition of monolayer-protected cluster films
    Michael C. Leopold
    Tran T. Doan
    Melissa J. Mullaney
    Andrew F. Loftus
    Christopher M. Kidd
    Journal of Applied Electrochemistry, 2015, 45 : 1069 - 1084
  • [35] Electrochemical and X-ray Photoelectron Spectroscopy Surface Characterization of Interchain-Driven Self-Assembled Monolayer (SAM) Reorganization
    Tricase, Angelo
    Imbriano, Anna
    Ditaranto, Nicoletta
    Macchia, Eleonora
    Picca, Rosaria Anna
    Blasi, Davide
    Torsi, Luisa
    Bollella, Paolo
    NANOMATERIALS, 2022, 12 (05)
  • [36] Electrochemical characterization of self-assembled monolayers on gold substrates derived from thermal decomposition of monolayer-protected cluster films
    Leopold, Michael C.
    Doan, Tran T.
    Mullaney, Melissa J.
    Loftus, Andrew F.
    Kidd, Christopher M.
    JOURNAL OF APPLIED ELECTROCHEMISTRY, 2015, 45 (10) : 1069 - 1084
  • [37] Electrochemical behavior of 4-pyridinethiolate self-assembled monolayer modified Au electrode and its application to the determination of ascorbic acid
    Lu, XQ
    La, BQ
    Xue, ZH
    Kang, JW
    CHINESE JOURNAL OF ANALYTICAL CHEMISTRY, 2003, 31 (06) : 686 - 688
  • [38] Characterization of a 1,4-dithiane gold self-assembled monolayer:: an electrochemical sensor for the cyt-c redox process
    de Sousa, JR
    Batista, AA
    Diógenes, ICN
    Andrade, GFS
    Temperini, MLA
    Lopes, LGF
    Moreira, ID
    JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2003, 543 (01): : 93 - 99
  • [39] Electrochemical polymerization of an aniline-terminated self-assembled monolayer on indium tin oxide electrodes and its effect on polyaniline electrodeposition
    Cruz-Silva, Rodolfo
    Nicho, Maria E.
    Resendiz, Mary C.
    Agarwal, Vivechana
    Castillon, Felipe F.
    Farias, Mario H.
    THIN SOLID FILMS, 2008, 516 (15) : 4793 - 4802
  • [40] Hydroxamation of gold surface via in-situ layer-by-layer functionalization of cysteamine self-assembled monolayer: Preparation and electrochemical characterization
    Shervedani, Reza Karimi
    Bagherzadeh, Mojtaba
    ELECTROCHIMICA ACTA, 2008, 53 (22) : 6293 - 6303
12345