A Polyoxometalate-Cyanometalate Multilayered Coordination Network

被引：29

作者：

Compain, Jean-Daniel ^{[1
]}

Nakabayashi, Koji ^{[1
]}

Ohkoshi, Shin-ichi ^{[1
,2
]}

机构：

[1] Univ Tokyo, Sch Sci, Dept Chem, Bunkyo Ku, Tokyo 1130033, Japan

[2] JST, CREST, Chiyoda Ku, Tokyo 1020075, Japan

来源：

INORGANIC CHEMISTRY | 2012年 / 51卷 / 09期

关键词：

PRUSSIAN BLUE ANALOGS; MAGNETIC-ORDERING TEMPERATURE; BOND-VALENCE PARAMETERS; BUILDING-BLOCKS; ORGANIC FRAMEWORKS; CRYSTAL-STRUCTURE; SPIN-CROSSOVER; DEGREES-C; STABILITY; COMPLEXES;

D O I：

10.1021/ic300263f

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of the epsilon-Keggin polyoxometalate (POM) [PMo12O36(OH)(4){La(H2O)(4)}(4)](5+) with Fe-II(CN)(6)(4-) under typical bench conditions at room temperature and ambient pressure has afforded the novel [epsilon-PMo12O37(OH)(3){La(H2O)(5)(Fe(CN)(6))(0.25)}(4)] network, which exhibits a three-dimensional multilayered structure. The compound has been fully characterized by synchrotron-radiation X-ray crystallography, IR spectroscopy, elemental analysis, and thermogravimetric analysis. This coordination network constitutes the first example of a cyanometalate bonded to a POM unit.

引用

页码：4897 / 4899

页数：3

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