Formation of self-assembled supramolecular polymers by anti-electrostatic anion-anion and halogen bonding interactions

被引:20
作者
Zapata, Fabiola [1 ]
Gonzalez, Lidia [1 ]
Bastida, Adolfo [2 ]
Bautista, Delia [3 ]
Caballero, Antonio [1 ]
机构
[1] Univ Murcia, Dept Quim Organ, Campus Espinardo, Murcia 30100, Spain
[2] Univ Murcia, Dept Quim Fis, Campus Espinardo, Murcia 30100, Spain
[3] Univ Murcia, Serv Apoyo Invest, Campus Espinardo, E-30071 Murcia, Spain
关键词
PHASE-TRANSITIONS; HYDROGEN; RECEPTORS; DERIVATIVES; CLUSTERS; WATER;
D O I
10.1039/d0cc02831b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We report here the formation of self-assembled supramolecular polymers in which the cooperative action of anti-electrostatic anion-anion and halogen-bonding interactions serve as a powerful driving force for the formation of large supramolecular polymers. DOSY-NMR, DLS, TEM, SEM and X-ray experiments provide evidence of the formation of supramolecular structures in solution and solid state.
引用
收藏
页码:7084 / 7087
页数:4
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共 41 条
  • [21] Trapped inorganic phosphate dimer
    Lakshminarayanan, P. S.
    Ravikumar, I.
    Suresh, E.
    Ghosh, Pradyut
    [J]. CHEMICAL COMMUNICATIONS, 2007, (48) : 5214 - 5216
  • [22] Anion-anion dimerization in tetrabutylammonium hydrogensulfate
    Light, ME
    Gale, PA
    Hursthouse, MB
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2001, 57 : O705 - O706
  • [23] Anion-anion one-dimensional chain formation within cationic channels in tetrabutylammonium dihydrogenphosphate dichloromethane solvate
    Light, ME
    Camiolo, S
    Gale, PA
    Hursthouse, MB
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2001, 57 : O727 - O729
  • [24] Crystal Structure of the Dihydrogen Phosphate Salt of Ozagrel (ozagrel=(E)-3-[4-(1H-Imidiazol-1-ylmethyl)phenyl]-2-Propenic Acid)
    Lou, Benyong
    Guo, Xia
    Lin, Qi
    [J]. JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2009, 39 (07) : 469 - 473
  • [25] Structural investigations of the phase transitions of tetramethylammonium sulfate
    Malchus, M
    Jansen, M
    [J]. ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1998, 54 : 494 - 502
  • [26] The Paradox of Hydrogen-Bonded Anion Anion Aggregates in Oxoanions: A Fundamental Electrostatic Problem Explained in Terms of Electrophilic•••Nucleophilic Interactions
    Mata, Ignasi
    Molins, Elies
    Alkorta, Ibon
    Espinosa, Enrique
    [J]. JOURNAL OF PHYSICAL CHEMISTRY A, 2015, 119 (01) : 183 - 194
  • [27] σ-Holes, π-holes and electrostatically-driven interactions
    Murray, Jane S.
    Lane, Pat
    Clark, Timothy
    Riley, Kevin E.
    Politzer, Peter
    [J]. JOURNAL OF MOLECULAR MODELING, 2012, 18 (02) : 541 - 548
  • [28] STRUCTURE OF TETRAMETHYLAMMONIUM DIHYDROGENORTHOPHOSPHATE MONOHYDRATE
    OHAMA, N
    MACHIDA, M
    NAKAMURA, T
    KUNIFUJI, Y
    [J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1987, 43 : 962 - 964
  • [29] σ-Hole Interactions: Perspectives and Misconceptions
    Politzer, Peter
    Murray, Jane S.
    [J]. CRYSTALS, 2017, 7 (07)
  • [30] Dihydrogen Phosphate Clusters: Trapping H2PO4- Tetramers and Hexamers in Urea-Functionalized Molecular Crystals
    Rajbanshi, Arbin
    Wan, Shun
    Custelcean, Radu
    [J]. CRYSTAL GROWTH & DESIGN, 2013, 13 (05) : 2233 - 2237