Formation of self-assembled supramolecular polymers by anti-electrostatic anion-anion and halogen bonding interactions

被引:20
|
作者
Zapata, Fabiola [1 ]
Gonzalez, Lidia [1 ]
Bastida, Adolfo [2 ]
Bautista, Delia [3 ]
Caballero, Antonio [1 ]
机构
[1] Univ Murcia, Dept Quim Organ, Campus Espinardo, Murcia 30100, Spain
[2] Univ Murcia, Dept Quim Fis, Campus Espinardo, Murcia 30100, Spain
[3] Univ Murcia, Serv Apoyo Invest, Campus Espinardo, E-30071 Murcia, Spain
关键词
PHASE-TRANSITIONS; HYDROGEN; RECEPTORS; DERIVATIVES; CLUSTERS; WATER;
D O I
10.1039/d0cc02831b
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
We report here the formation of self-assembled supramolecular polymers in which the cooperative action of anti-electrostatic anion-anion and halogen-bonding interactions serve as a powerful driving force for the formation of large supramolecular polymers. DOSY-NMR, DLS, TEM, SEM and X-ray experiments provide evidence of the formation of supramolecular structures in solution and solid state.
引用
收藏
页码:7084 / 7087
页数:4
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