Synthesis of a Benzenethiol-derivatized Porphyrin for Self-assembly

被引：8
|
作者：
Wan Jicheng [1 ]
Sun Huiqian [1 ]
Huang Xuebin [1 ]
机构：
[1] Beijing Inst Technol, Sch Chem, Beijing 100081, Peoples R China
来源：
CHINESE JOURNAL OF CHEMISTRY | 2012年 / 30卷 / 08期
关键词：
porphyrin; thiol; self-assembly; MOLECULAR SCALE WIRES; INFORMATION-STORAGE; GOLD; FILMS; MONOLAYERS; METALLOPORPHYRINS; ETHYNYLENE)S; ORIENTATION; REDUCTION; DIOXYGEN;
D O I：
10.1002/cjoc.201200345
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The synthesis of a benzenethiol-derivatized porphyrin for flat-lying self-assembly on gold substrates is described. Acetyl protected thiol is not stable enough in Pd-catalyzed reactions. While acrylate derivatives protected thiol group shows good tolerance in Pd-catalyzed borylations and Suzuki-Miyaura coupling reactions and no catalyst poisoning was observed.
引用
收藏
页码：1841 / 1844
页数：4
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