Synthesis, structure, photochromic, and fluorescent imaging properties of sodium-3,3′-azobis(1,2,4-triazole)

被引：4

作者：

Yang, Meng ^{[1
]}

Chen, Shuang ^{[1
]}

Qiu, Yan-Xuan ^{[1
]}

Chen, Wen-Bin ^{[1
]}

Lin, Jiao-Min ^{[1
]}

Yan, Hua ^{[1
]}

Yang, Zhen-Jie Ou ^{[1
]}

Dong, Wen ^{[1
]}

机构：

[1] Guangzhou Univ, Dept Chem, Guangzhou 510006, Guangdong, Peoples R China

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2012年 / 65卷 / 24期

基金：

中国国家自然科学基金;

关键词：

3; 3'-Azobis(1; 2; 4-triazole); Crystal structure; Photoluminescence; Photochromism; PHOTOCHEMISTRY; MOLECULES; POLYMER;

D O I：

10.1080/00958972.2012.736971

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A crystal of [Na2(ABT)?.?5H2O] (ABT?=?3,3'-azobis(1,2,4-triazole)) (1) was characterized by single-crystal X-ray diffraction. Complex 1 features a 1-D chain and each ABT2- is a mu 1,2,6 bridge with three triazole nitrogen atoms coordinating to three different sodium(I). Aqueous solution of 1 (6.0?x?10-5?mol?L-1) shows photochromism. Fluorescence of solid 1 displays green photoluminescence under UV-light or laser irradiation and can be employed to label onion cell.

引用

页码：4255 / 4262

页数：8

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