Fabrication of trimethylphosphine-functionalized anion exchange membranes for desalination application via electrodialysis process

被引:11
作者
Khan, Muhammad Imran [1 ]
Shanableh, Abdallah [1 ]
Osman, Sameh M. [2 ]
Lashari, Mushtaq Hussain [3 ]
Manzoor, Suryyia [4 ]
ur Rehman, Aziz [5 ]
Luque, Rafael [6 ,7 ]
机构
[1] Univ Sharjah, Res Inst Sci & Engn RISE, 27272, Sharjah, U Arab Emirates
[2] King Saud Univ, Coll Sci, Dept Chem, POB 2455, Riyadh 11451, Saudi Arabia
[3] Islamia Univ Bahawalpur, Dept Zool, Bahawalpur 63100, Pakistan
[4] Bahauddin Zakariya Univ, Inst Chem Sci, Multan 60800, Pakistan
[5] Islamia Univ Bahawalpur, Dept Chem, Bahawalpur 63100, Pakistan
[6] Univ Cordoba, Dept Quim Organ, Edificio Marie Curie C3,Campus de Rabanales,Ctra, Cordoba E-14014, Spain
[7] RUDN Univ, Peoples Friendship Univ Russia, 6 Miklukho Maklaya Str, Moscow 117198, Russia
关键词
Trimethylphosphine; Electrodialysis; BPPO; Water uptake; Anion exchange membranes; ACID RECOVERY; WASTE-WATER; BPPO; PERFORMANCE; SEPARATION; EFFICIENCY;
D O I
10.1016/j.chemosphere.2022.136330
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The design of conductive, improved durable and selective anion exchange membranes (AEMs) for desalination application via electrodialysis (ED) process is critical for a more sustainable future. This work reports the design of a series of homogeneous trimethylphosphine (TMP)-functionalized anion exchange membranes (AEMs) for desalination application via electrodialysis (ED) process. Physico-chemical characterization and electrochemical performance of the trimethylphosphine-functionalized anion exchange membranes was conducted and the ac-tivity found to be tuned by varying the quantity of trimethylphosphine into the membrane architecture. For anion exchange membranes M1 to M4, the ion exchange capacity (IEC) was increased from 1.35 to 2.16 mmol/g, water uptake (WR) from 4.30 to 17.72%, linear expansion ratio (LER) from 3.70 to 12.50% with enhancing the quantity of trimethylphosphine into the polymer architecture. The ionic resistance decreased from 15.14 to 2.61 Omega cm2 with increasing quantities of trimethylphosphine whereas transport number increased from 0.98 to 0.99. The performance of synthesized trimethylphosphine-functionalized anion exchange membranes in desalination of NaCl was evaluated via electrodialysis process (flux of 3.42 mol/m2. h and current efficiency of 64.30%). Results showed that the prepared trimethylphosphine-functionalized membrane (optimum M4) possess improved desalination performance as compared to commercial membrane Neosepta AMX under identical experimental conditions.
引用
收藏
页数:8
相关论文
共 48 条
[1]   An alkaline stable anion exchange membrane for electro-desalination [J].
Alam, Md Mofasserul ;
Hossain, Masem ;
Mei, Ying ;
Jiang, Chenxiao ;
Wang, Yaoming ;
Tang, Chuyang Y. ;
Xu, Tongwen .
DESALINATION, 2021, 497
[2]   Mechanically Stable Poly(arylene ether) Anion Exchange Membranes Prepared from Commercially Available Polymers for Alkaline Electrochemical Devices [J].
Arges, Christopher G. ;
Wang, Lihui ;
Jung, Min-suk ;
Ramani, Vijay .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2015, 162 (07) :F686-F693
[3]   Separation of Copper Ions from Synthetically Prepared Electroplating Wastewater at Different Operating Conditions using Electrodialysis [J].
Caprarescu, Simona ;
Purcar, Violeta ;
Vaireanu, Danut-Ionel .
SEPARATION SCIENCE AND TECHNOLOGY, 2012, 47 (16) :2273-2280
[4]   Transport limitations in ion exchange membranes at low salt concentrations [J].
Dlugolecki, Piotr ;
Anet, Benoit ;
Metz, Sybrand J. ;
Nijmeijer, Kitty ;
Wessling, Matthias .
JOURNAL OF MEMBRANE SCIENCE, 2010, 346 (01) :163-171
[5]   Comparison of transport properties of monovalent anions through anion-exchange membranes [J].
Elattar, A ;
Elmidaoui, A ;
Pismenskaia, N ;
Gavach, C ;
Pourcelly, G .
JOURNAL OF MEMBRANE SCIENCE, 1998, 143 (1-2) :249-261
[6]   Temperature resistant cross-linked brominated poly phenylene oxide-functionalized graphene oxide nanocomposite anion exchange membrane for desalination [J].
Goel, Priya ;
Mandal, Priyabrata ;
Bhuvanesh, E. ;
Shahi, Vinod K. ;
Chattopadhyay, Sujay .
SEPARATION AND PURIFICATION TECHNOLOGY, 2021, 255
[7]   Preparation and characterization of mono-valent ion selective polypyrrole composite ion-exchange membranes [J].
Gohil, G. S. ;
Binsu, V. V. ;
Shahi, Vinod K. .
JOURNAL OF MEMBRANE SCIENCE, 2006, 280 (1-2) :210-218
[8]   Comparative studies on electrochemical characterization of homogeneous and heterogeneous type of ion-exchange membranes [J].
Gohil, GS ;
Shahi, VK ;
Rangarajan, R .
JOURNAL OF MEMBRANE SCIENCE, 2004, 240 (1-2) :211-219
[9]   Preparation and characterization of organic-inorganic hybrid anion-exchange membranes for electrodialysis [J].
Khan, Moonis Ali ;
Kumar, Mahendra ;
Alothman, Zeid Abdullah .
JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2015, 21 :723-730
[10]   Adsorption of Methyl Orange from an Aqueous Solution onto a BPPO-Based Anion Exchange Membrane [J].
Khan, Muhammad Imran ;
Shanableh, Abdallah ;
Elboughdiri, Noureddine ;
Lashari, Mushtaq Hussain ;
Manzoor, Suryyia ;
Shahida, Shabnam ;
Farooq, Nosheen ;
Bouazzi, Yassine ;
Rejeb, Sarra ;
Elleuch, Zied ;
Kriaa, Karim ;
Rehman, Aziz Ur .
ACS OMEGA, 2022, :26788-26799