Synthesis, Structures, Electrochemistry, and Spectroscopy of Two Ruthenium(II) Complexes Containing [1,2,3]Triazolo[1, 5-a]pyridine

被引：9

作者：

Xiang, Jing ^{[1
]}

Wu, Jia-Shou ^{[2
]}

机构：

[1] Yangtze Univ, Coll Chem & Environm Engn, Jinzhou 434020, Hubei, Peoples R China

[2] Taizhou Univ, Sch Pharmaceut & Chem Engn, Taizhou 317000, Peoples R China

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2013年 / 639卷 / 3-4期

关键词：

Ruthenium; 1; 2; 3]Triazoles; Luminescence properties; IR specroscopy; RAY CRYSTAL-STRUCTURES; LUMINESCENCE RIGIDOCHROMISM; HYDRIDE COMPLEXES; LIGANDS; PHOTOCHEMISTRY; PROTONATION; COBALT(II); CHEMISTRY; HYDRAZONE; BEHAVIOR;

D O I：

10.1002/zaac.201200378

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of 3-(2-pyridyl)1,2,3triazolo[1, 5-a]pyridine (L1) with [RuII(CO)(PPh3)3(H)2] or [RuII(DMSO)4(Cl)2] produced the mononuclear compounds [RuII(L1)(CO)(H)(PPh3)2](PF6) (1) and [RuII(L1)3](PF6)2 (2), respectively, which were characterized by IR, UV, CV, and 1H NMR spectroscopy as well as ESI mass spectrometry. The crystal structure of 1 was determined by X-ray crystallography and the luminescence properties of both compounds were investigated.

引用

页码：606 / 610

页数：5

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