The role of nitrogen-donor ligands in the palladium-catalyzed polyketones synthesis

被引:108
作者
Durand, J [1 ]
Milani, B [1 ]
机构
[1] Univ Trieste, Dipartimento Sci Chim, I-34127 Trieste, Italy
关键词
nitrogen-donor ligand; palladium; polymerization; polyketone; olefin; homogeneous catalysis;
D O I
10.1016/j.ccr.2005.08.012
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
During the last decade there has been increased interest in the development of homogeneous catalytic systems to promote homo- or copolymerization reactions of unsaturated hydrocarbons. This review is focused on systems based on palladium complexes with nitrogen-donor ligands and on their application as catalysts (or precatalysts) for co- and terpolymerization of carbon monoxide and olefins. Detailed catalytic performance is reported (productivity, molecular weight values and stereoregularity of the copolymers) allowing comparison between different systems. Particular attention will be addressed to the relationship between catalyst structure and structural features of the polymers synthesized. A comment on the mechanism involved in the various reactions is also given. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:542 / 560
页数:19
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