Organometallic derivatives at the core of phosphorus-containing dendrimers

被引：24
作者：
Turrin, CO [1 ]
Donnadieu, B [1 ]
Caminade, AM [1 ]
Majoral, JP [1 ]
机构：
[1] CNRS, Chim Coordinat Lab, F-31077 Toulouse, France
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2005年 / 631卷 / 13-14期
关键词：
dendrimers; phosphorus; ferrocene; hydrazones; S ligands;
D O I：
10.1002/zaac.200500213
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The synthesis of a new family of phosphorus-containing dendrimers is described up to the fourth generation. These compounds are built from a ferrocene core substituted by two electron withdrawing P=N-P=S linkages, which dramatically modify the electrochemical properties of the ferrocene. These substituents are able to complex instantaneously group II metals, and the structure of one of these complexes has been determined by X-ray diffraction.
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收藏
页码：2881 / 2887
页数：7
相关论文
共 44 条
[1]   Light-harvesting dendrimers [J].
Adronov, A ;
Fréchet, JMJ .
CHEMICAL COMMUNICATIONS, 2000, (18) :1701-1710
[2]  
Alonso B, 2002, ADV DENDR MACROMOL, V5, P89
[3]   COMPLETION AND REFINEMENT OF CRYSTAL-STRUCTURES WITH SIR92 [J].
ALTOMARE, A ;
CASCARANO, G ;
GIACOVAZZO, C ;
GUAGLIARDI, A .
JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1993, 26 (pt 3) :343-350
[4]  
ASTRUC D, 2002, CHEM REV, V102, P3717
[5]   Designing dendrimers based on transition metal complexes. Light-harvesting properties and predetermined redox patterns [J].
Balzani, V ;
Campagna, S ;
Denti, G ;
Juris, A ;
Serroni, S ;
Venturi, M .
ACCOUNTS OF CHEMICAL RESEARCH, 1998, 31 (01) :26-34
[6]   Ruthenium hydride and dihydrogen complexes with dendrimeric multidentate ligands [J].
Bardaji, M ;
Caminade, AM ;
Majoral, JP ;
Chaudret, B .
ORGANOMETALLICS, 1997, 16 (15) :3489-3497
[7]   Phosphorus-containing dendrimers as multidentate ligands: Palladium, platinum, and rhodium complexes [J].
Bardaji, M ;
Kustos, M ;
Caminade, AM ;
Majoral, JP ;
Chaudret, B .
ORGANOMETALLICS, 1997, 16 (03) :403-410
[8]   Dendrimers containing zwitterionic [phosphonium anionic zirconocene(IV)] complexes [J].
Cadierno, V ;
Igau, A ;
Donnadieu, B ;
Caminade, AM ;
Majoral, JP .
ORGANOMETALLICS, 1999, 18 (09) :1580-1582
[9]   Nanomaterials based on phosphorus dendrimers [J].
Caminade, AM ;
Majoral, JP .
ACCOUNTS OF CHEMICAL RESEARCH, 2004, 37 (06) :341-348
[10]   Organometallic derivatives of phosphorus-containing dendrimers. Synthesis, properties and applications in catalysis [J].
Caminade, AM ;
Maraval, V ;
Laurent, R ;
Majoral, JP .
CURRENT ORGANIC CHEMISTRY, 2002, 6 (08) :739-774
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