Organometallic derivatives at the core of phosphorus-containing dendrimers

被引：24

作者：

Turrin, CO ^{[1
]}

Donnadieu, B ^{[1
]}

Caminade, AM ^{[1
]}

Majoral, JP ^{[1
]}

机构：

[1] CNRS, Chim Coordinat Lab, F-31077 Toulouse, France

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2005年 / 631卷 / 13-14期

关键词：

dendrimers; phosphorus; ferrocene; hydrazones; S ligands;

D O I：

10.1002/zaac.200500213

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The synthesis of a new family of phosphorus-containing dendrimers is described up to the fourth generation. These compounds are built from a ferrocene core substituted by two electron withdrawing P=N-P=S linkages, which dramatically modify the electrochemical properties of the ferrocene. These substituents are able to complex instantaneously group II metals, and the structure of one of these complexes has been determined by X-ray diffraction.

引用

页码：2881 / 2887

页数：7

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