Effect of N ancillary ligands on the structure, nuclearity and magnetic behavior of Cu(II)-pyrazolecarboxylate complexes

被引：13

作者：

Cheng, Meiling ^{[1
,2
]}

Sun, Lin ^{[1
,2
]}

Han, Wei ^{[1
,2
]}

Wang, Shen ^{[1
,2
]}

Liu, Qi ^{[1
,2
,3
]}

Sun, Xiaoqiang ^{[1
,2
]}

Xi, Haitao ^{[1
,2
]}

机构：

[1] Changzhou Univ, Sch Petrochem Engn, Changzhou 213164, Peoples R China

[2] Changzhou Univ, Jiangsu Key Lab Adv Catalyt Mat & Technol, Changzhou 213164, Peoples R China

[3] Nanjing Univ, State Key Lab Coordinat Chem, Nanjing 210093, Jiangsu, Peoples R China

来源：

NEW JOURNAL OF CHEMISTRY | 2016年 / 40卷 / 12期

基金：

中国国家自然科学基金;

关键词：

ELECTRON-PARAMAGNETIC-RESONANCE; PARTICULATE METHANE MONOOXYGENASE; TRINUCLEAR COPPER(II) COMPLEXES; X-RAY-STRUCTURE; CRYSTAL-STRUCTURES; COORDINATION POLYMERS; LUMINESCENT PROPERTIES; METAL-COMPLEXES; 5-METHYL-1H-PYRAZOLE-3-CARBOXYLIC ACID; II COMPLEX;

D O I：

10.1039/c6nj02338j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

In the absence/presence of different N ancillary ligands, four copper(II)-pyrazolecarboxylate complexes, [Cu(HMPCA)(2)(lmH)(2)]center dot 2H(2)O (1), (Cu-2(MPCA)(2)(H2O)(4)] (2), [Cu-2(MPCA)(2)(4,4'-bpy)(H2O)(2)](n)center dot 5nH(2)O (3) and [Cu-3(MPCA)(3)(Phen)(3)](2)center dot 2EtOH.15H(2)O (4) (H(2)MPCA = 5-methyl-1H-pyrazole-3-carboxylic acid, lmH = imidazole, 4,4'-bpy = 4,4'-bipyridine and Phen = 1,10-phenanthroline) were obtained. All complexes have been structurally characterized. Compounds 2 and 3 containing the same bis(mu-pyrazolato)dicopper(II) planes range from dinuclear to 1D polymer. Trinuclear complex 4 contains the first reported cyclic-trinuclear copper(II)-pyrazolato structure without any mu(3) ligand core. Magnetic susceptibility data show that complexes 2-4 exhibit antiferromagnetic couplings between the adjacent magnetic centers.

引用

页码：10504 / 10511

页数：8

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