Synthesis and characterization of coordination polymers of Zn(II) with 1,3-bis(4-pyridyl)propane and 4,4′-pyridine ligands

被引：33
作者：
Lee, TW [1 ]
Lau, JPK [1 ]
Wong, WT [1 ]
机构：
[1] Univ Hong Kong, Dept Chem, Hong Kong, Hong Kong, Peoples R China
来源：
POLYHEDRON | 2004年 / 23卷 / 06期
关键词：
zinc; 1,3-bis(4-pyridyl)propane; 4,4 '-pyridine; polymeric network; X-ray crystallography;
D O I：
10.1016/j.poly.2003.12.020
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two new metal-coordination polymers, [Zn-2(bpy)(OAc)(4)](n) (1) and [Zn(bpp)(NO3)(2)](n) (2) were prepared by the layering method using Zn(11) ions, bpy and bpp ligands, and structurally characterized by single-crystal X-ray diffraction analyses. Complexes 1 and 2 were both found to be one-dimensional coordination polymers. The periodic length of the chain between two alternate Zn(II) ions in compound I is 26.92 Angstrom which is more than twice the length of compound 2 (26.92 > 11.92 x 2). (C) 2004 Elsevier Ltd. All rights reserved.
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页码：999 / 1002
页数：4
相关论文
共 21 条
[1]   SIR92 - a program for automatic solution of crystal structures by direct methods [J].
ALTOMARE, A ;
CASCARANO, G ;
GIACOVAZZO, G ;
GUAGLIARDI, A ;
BURLA, MC ;
POLIDORI, G ;
CAMALLI, M .
JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1994, 27 :435-435
[2]  
[Anonymous], 1985, TEXSAN CRYST STRUCT
[3]   Studies of the construction of coordination polymers using linear pyridyl-donor ligands [J].
Batten, SR ;
Jeffery, JC ;
Ward, MD .
INORGANICA CHIMICA ACTA, 1999, 292 (02) :231-237
[4]  
BEURSKENS BT, 1994, TECHNICAL REPORT CRY
[5]   One- and two-dimensional coordination polymers of zinc(II) with pyrazine. Solid state reactions and decomposition kinetics of the interconversion reactions [J].
Bourne, SA ;
Kilkenny, M ;
Nassimbeni, LR .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 2001, (08) :1176-1179
[6]  
Cheetham AK, 1999, ANGEW CHEM INT EDIT, V38, P3268, DOI 10.1002/(SICI)1521-3773(19991115)38:22<3268::AID-ANIE3268>3.0.CO
[7]  
2-U
[8]   Two novel three-dimensional coordination polymers with [Ag(CN)2] as bridging ligands:: synthesis and structural characterization of {KMn[Ag(CN)2]3(H2O)}n and {Mn[Ag(CN)2]2(bpy)2}n (bpy=4,4′-bipyridine) [J].
Dong, W ;
Wang, QL ;
Si, SF ;
Liao, DZ ;
Jiang, ZH ;
Yan, SP ;
Cheng, P .
INORGANIC CHEMISTRY COMMUNICATIONS, 2003, 6 (07) :873-876
[9]   Crystal engineering of NLO materials based on metal-organic coordination networks [J].
Evans, OR ;
Lin, WB .
ACCOUNTS OF CHEMICAL RESEARCH, 2002, 35 (07) :511-522
[10]   One- and two-dimensional metal-dicyanamido complexes with a flexible bridging co-ligand: structural and magnetic properties [J].
Gao, EQ ;
Bai, SQ ;
Wang, ZM ;
Yan, CH .
DALTON TRANSACTIONS, 2003, (09) :1759-1764
123