Pd-Co/MWCNTs Catalyst for Electrooxidation of Hydrazine in Alkaline Solution

被引：16
作者：
Liu, J. [1 ]
Liu, R. [1 ]
Yuan, C. L. [1 ]
Wei, X. P. [1 ]
Yin, J. L. [1 ]
Wang, G. L. [1 ]
Cao, D. X. [1 ]
机构：
[1] Harbin Engn Univ, Coll Mat Sci & Chem Engn, Minist Educ, Key Lab Superlight Mat & Surface Technol, Harbin 150001, Peoples R China
来源：
FUEL CELLS | 2013年 / 13卷 / 05期
关键词：
Carbon Nanotubes; Cobalt; Electrocatalyst; Hydrazine Electrooxidation; Palladium; OXYGEN REDUCTION REACTION; MULTIWALLED CARBON NANOTUBES; FUEL-CELL; ELECTROCATALYTIC OXIDATION; EXCHANGE MEMBRANE; HYDROGEN STORAGE; NANOPARTICLES; PALLADIUM; COMPOSITE; CO;
D O I：
10.1002/fuce.201200124
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
Multiwall carbon nanotubes supported Pd-Co electrocatalysts (Pd-Co/MWCNTs) for hydrazine electrooxidation in alkaline electrolytes were prepared. Their morphology and structure were characterized by scanning electron microscopy, transmission electron microscope, and X-ray diffraction. The effect of the mass ratio of Pd to Co on the catalytic performance was examined via cyclic voltammetric and chronoamperometric measurements. The Pd-Co/MWCNTs with a mass ratio of 1:1 for Pd:Co shows higher catalytic performance than both Pd/MWCNTs and Co/MWCNTs and it has good stability for catalyzing the electrooxidation of hydrazine. The gas collection measurements indicated that hydrazine electrooxidation on Pd-Co/MWCNTs proceeded via a near 4-electron pathway.
引用
收藏
页码：903 / 909
页数：7
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