Cs3Zn6B9O21: A Chemically Benign Member of the KBBF Family Exhibiting the Largest Second Harmonic Generation Response

被引：338

作者：

Yu, Hongwei ^{[1
,2
,3
,4
]}

Wu, Hongping ^{[1
,2
,3
]}

Pan, Shilie ^{[1
,2
,3
]}

Yang, Zhihua ^{[1
,2
,3
]}

Hou, Xueling ^{[1
,2
,3
]}

Su, Xin ^{[1
,2
,3
]}

Jing, Qun ^{[1
,2
,3
,4
]}

Poeppelmeier, Kenneth R. ^{[5
]}

Rondinelli, James M. ^{[6
]}

机构：

[1] Key Lab Funct Mat & Devices Special Environm CAS, Urumqi 830011, Peoples R China

[2] Xinjiang Tech Inst Phys & Chem CAS, Urumqi 830011, Peoples R China

[3] Xinjiang Key Lab Elect Informat Mat & Devices, Urumqi 830011, Peoples R China

[4] Univ Chinese Acad Sci, Beijing 100049, Peoples R China

[5] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA

[6] Drexel Univ, Dept Mat Sci & Engn, Philadelphia, PA 19104 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2014年 / 136卷 / 04期

基金：

中国国家自然科学基金; 美国国家科学基金会;

关键词：

NONLINEAR-OPTICAL CRYSTAL; ALKALINE BERYLLIUM BORATE; BOND-VALENCE PARAMETERS; UV; PEROVSKITE; LASER; RB;

D O I：

10.1021/ja4117389

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Nonlinear optical (NLO) crystals are essential materials for generation of coherent UV light in solid state lasers. KBBF is the only material that can achieve coherent light below 200 nm by direct second harmonic generation (SHG). However, its strong layer habits and the high toxicity of the beryllium oxide powders required for synthesis limit its application. By substituting Be with Zn and connecting adjacent [Zn2BO3O2](infinity) layers by B3O6 groups, a new UV nonlinear optical material, Cs3Zn6B9O21, was synthesized. It overcomes the processing limitations of KBBF and exhibits the largest SHG response in the KBBF family.

引用

页码：1264 / 1267

页数：4

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