exo-binding of Na+ between two fused calix[4]arenes and endo binding of Na+ within the calix[4]arene cones in the disodium salt of 1,3-dimethyl ether p-tert-butylcalix[4]arene

被引：31
|
作者：
Dubberley, SR [1 ]
Blake, AJ [1 ]
Mountford, P [1 ]
机构：
[1] UNIV NOTTINGHAM,DEPT CHEM,NOTTINGHAM NG7 2RD,ENGLAND
来源：
CHEMICAL COMMUNICATIONS | 1997年 / 17期
关键词：
D O I：
10.1039/a701639e
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Reaction of 1,3-dimethyl ether p-tert-butylcalix[4]arene (H2L) with sodium hydride in tetrahydrofuran affords the dimeric metallocalixarene species [Na2L](2) which possesses a novel structure in which the Na+ ions are coordinated in two very different environments.
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收藏
页码：1603 / 1604
页数：2
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