Cu doped V2O5 flowers as cathode material for high-performance lithium ion batteries

被引:5
|
作者
Yu, Hong [1 ,2 ]
Rui, Xianhong [1 ,2 ]
Tan, Huiteng [1 ,2 ]
Chen, Jing [1 ]
Huang, Xin [1 ]
Xu, Chen [1 ,2 ]
Liu, Weiling [1 ]
Yu, Denis Y. W. [2 ]
Hng, Huey Hoon [1 ]
Hoster, Harry E. [2 ]
Yan, Qingyu [1 ,2 ,3 ]
机构
[1] Nanyang Technol Univ, Sch Mat Sci & Engn, Singapore 639798, Singapore
[2] Nanyang Technol Univ, TUM CREATE Ctr Electromobil, Singapore 639798, Singapore
[3] Nanyang Technol Univ, Energy Res Inst, Singapore 637459, Singapore
基金
新加坡国家研究基金会;
关键词
VANADIUM PENTOXIDE; HOST MATERIALS; INTERCALATION; ELECTRODES; STORAGE; OXIDES; COMPOSITES; OXIDATION; INSERTION; SPHERES;
D O I
10.1039/c3nr00548h
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Hierarchical Cu doped vanadium pentoxide (V2O5) flowers were prepared via a simple hydrothermal approach followed by an annealing process. The flower precursors are self-assembled with 1D nanobelts surrounding a central core. The morphological evolution is investigated and a plausible mechanism is proposed. As the cathode material for lithium ion batteries, the Cu doped V2O5 samples exhibit improved electrochemical performance compared to the un-doped ones. Among them Cu0.02V1.98O5 delivered higher reversible specific capacities, better cycling stabilities and excellent rate capabilities, e. g. 97 mA h g(-1) at 20.0 C.
引用
收藏
页码:4937 / 4943
页数:7
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