Synthesis of O,O-Diethyl Arylthiophosphonate from O-Aryl-O,O-diethylthiophosphate

被引:8
|
作者
Dieng, Thierno [1 ]
Fraix, Aurore [1 ]
Salauen, Jean-Yves [1 ]
Dez, Isabelle [2 ]
Gebbink, Robertus. J. M. Klein [3 ]
van Koten, Gerard [3 ]
Jaffres, Paul-Alain [1 ]
机构
[1] Univ Europeennee Bretagne, Fed Rech SclnBios, CNRS UMR 6521 CEMCA, Univ Brest, F-29238 Brest, France
[2] Univ Caen, LCMT, UMR CNRS 6507, ENSICAEN, F-14050 Caen, France
[3] Univ Utrecht, Fac Sci, NL-3584 CH Utrecht, Netherlands
关键词
phosphorylation; metallation; phenols; rearrangement;
D O I
10.1055/s-0028-1087362
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The synthesis of O,O-diethyl 2-hydroxyarylthiophosphonate is reported by using a [1,3]-rearrangement. This method is achieved in high yield from ortho-bromophenols derivatives by a two-step process
引用
收藏
页码:3121 / 3124
页数:4
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