Molecular amino-phosphonate cobalt-lanthanide clusters

被引：85

作者：

Pineda, Eufemio Moreno

Tuna, Floriana

Pritchard, Robin G.

Regan, Andrew C.

Winpenny, Richard E. P. ^{[1
]}

McInnes, Eric J. L.

机构：

[1] Univ Manchester, Sch Chem, Manchester M13 9PL, Lancs, England

来源：

CHEMICAL COMMUNICATIONS | 2013年 / 49卷 / 34期

基金：

英国工程与自然科学研究理事会;

关键词：

MAGNETIC-PROPERTIES; PIVALATE COMPLEXES; CAGES; LIGAND; CORE; LN;

D O I：

10.1039/c3cc40907d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The use of 1-amino-1-cyclohexyl phosphonic acid, a functionalised phosphonate, leads to the synthesis of two new structural types for 3d-4f phosphonate cages with unusual structural cores and which show high magnetocaloric effects.

引用

页码：3522 / 3524

页数：3

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