Effects of the Sintering Temperature on the Properties of Ce0.85Gd0.1Ca0.05O2-δ Electrolyte Materials for SOFC

被引:0
作者
Kim, Hyunju-Ju [1 ]
Lee, Seung-Hwan [1 ]
Kim, Seung-Hyun [1 ]
Lee, Sung-Gap [2 ]
Lee, Young-Hie [1 ]
机构
[1] Kwangwoon Univ, Dept Elect Mat Engn, Seoul, South Korea
[2] Gyeongsang Natl Univ, Dept Ceram Engn, Jinju, South Korea
关键词
Ceramics; impedance spectroscopy; ionic conductivity; SOFC; OPTIMAL-DESIGN; OXIDE; INTERCONNECTS; CONVERTER; FILMS; CELLS;
D O I
10.1080/10584587.2012.741453
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
Ca properties in the sintering behavior of gadolinia-doped ceria were investigated. Their structures and conductivities were characterized by X-ray diffraction, scanning electron microscopy, and AC impedance spectroscopy. All the electrolytes were found to be of single phase with a cubic fluorite structure. AC impedance measurements showed that the conductivities for Ce0.85Gd0.10Ca0.05O2-delta sample increased by increasing the sintering temperature. At 1500 degrees C the Ce0.85Gd0.10Ca0.05O2-delta had low resistivity values, high conductivity, and low activation energy.
引用
收藏
页码:71 / 76
页数:6
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