Stereoselective Rhodium-Catalyzed Isomerization of Stereoisomeric Mixtures of Arylalkenes

被引：2
|
作者：
Yang, Hongxuan [1 ]
Dong, Wenke [1 ]
Wang, Wencan [1 ]
Li, Tao [1 ]
Zhao, Wanxiang [1 ]
机构：
[1] Hunan Univ, State Key Lab Chemo Biosensing & Chemometr, Coll Chem & Chem Engn, Changsha 410082, Hunan, Peoples R China
来源：
SYNTHESIS-STUTTGART | 2020年 / 52卷 / 19期
基金：
中国国家自然科学基金;
关键词：
isomerization; stereoselectivity; rhodium; alkene; interconversion; DEHYDROGENATIVE BORYLATION; PALLADIUM(II)-CATALYZED ISOMERIZATION; WITTIG REACTION; ALKENES; MONOISOMERIZATION; VINYLARENES; PINACOLBORANE; NANOPARTICLES; EFFICIENT; 1-ALKENES;
D O I：
10.1055/s-0040-1707166
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A new efficient method for the synthesis of a high ratio of E-alkenes from E/Zmixtures of alkenes with B(2)pin(2) in the presence of a rhodium catalyst is described. This reaction features mild reaction conditions, broad functional group tolerance, and highly great application potential.
引用
收藏
页码：2833 / 2840
页数：8
相关论文
共 50 条
  • [41] Rhodium-catalyzed methylenation reaction
    Paquet, V
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2003, 225 : U317 - U317
  • [42] Rhodium-catalyzed intermolecular hydroamination
    Ickes, Andrew
    Ensign, Seth
    Gupta, Anil
    Hull, Kami
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2015, 250
  • [43] Rhodium-Catalyzed Asymmetric Arylation
    Tian, Ping
    Dong, Han-Qing
    Lin, Guo-Qiang
    ACS CATALYSIS, 2012, 2 (01): : 95 - 119
  • [44] Rhodium-catalyzed decarbonylation of aldoses
    Monrad, Rune Nygaard
    Madsen, Robert
    JOURNAL OF ORGANIC CHEMISTRY, 2007, 72 (25): : 9782 - 9785
  • [45] Rhodium-catalyzed modification of phthalocyanines
    Ali, Hasrat
    van Lier, Johan E.
    TETRAHEDRON LETTERS, 2013, 54 (23) : 2956 - 2959
  • [46] Rhodium-catalyzed Decarbonylation of Acylsilanes
    Yoshida, Tomoki
    Kodama, Takuya
    Tobisu, Mamoru
    ASIAN JOURNAL OF ORGANIC CHEMISTRY, 2022, 11 (12)
  • [47] Rhodium-catalyzed cyclocarbonylation of azobenzene
    Zhou, DY
    Koike, T
    Suetsugu, S
    Onitsuka, K
    Takahashi, S
    INORGANICA CHIMICA ACTA, 2004, 357 (10) : 3057 - 3063
  • [48] KINETIC RESOLUTION OF 4-HYDROXY-2-CYCLOPENTENONE BY RHODIUM-CATALYZED ASYMMETRIC ISOMERIZATION
    KITAMURA, M
    MANABE, K
    NOYORI, R
    TAKAYA, H
    TETRAHEDRON LETTERS, 1987, 28 (40) : 4719 - 4720
  • [49] Azaphosphatriptycene in rhodium-catalyzed hydroformylation
    Cao, Yu
    Napoline, Jonathan
    Bacsa, John
    Sadighi, Joseph
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2018, 255
  • [50] Rhodium-catalyzed hydroaminomethylation of cyclopentadiene
    Behr, Arno
    Levikov, Denys
    Nuerenberg, Edward
    RSC ADVANCES, 2015, 5 (75) : 60667 - 60673
12345