Palladium-tetraphosphine complex: An efficient catalyst for allylic substitution and Suzuki cross-coupling

被引：31
|
作者：
Feuerstein, M [1 ]
Laurenti, D [1 ]
Doucet, H [1 ]
Santelli, M [1 ]
机构：
[1] Fac Sci & Tech St Jerome, Lab Synth Organ, CNRS, F-13397 Marseille 20, France
来源：
SYNTHESIS-STUTTGART | 2001年 / 15期
关键词：
palladium; phosphines; catalysis; alkylation; amination;
D O I：
10.1055/s-2001-18430
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A new tetraphosphine, the cis-cis-cis-1,2,3,4-tetrakis(diphenylphosphinomethyl)cyclopentane (Tedicyp) has been synthesized and used in palladium-catalyzed reactions. This tetraphosphine in combination with [Pd(C3H5)Cl](2) affords a very efficient catalyst for coupling reactions. Turnover numbers of 980 000 for allylic amination. 9 800 000 for allylic alkylation and 97 000 000 for Suzuki cross-coupling can be obtained in the presence of this catalyst.
引用
收藏
页码：2320 / 2326
页数：7
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