Functional tolerance in an isoreticular series of highly porous metal-organic frameworks

被引：18

作者：

Kim, Min ^{[1
]}

Boissonnault, Jake A. ^{[1
]}

Allen, Corinne A. ^{[1
]}

Dau, Phuong V. ^{[1
]}

Cohen, Seth M. ^{[1
]}

机构：

[1] Univ Calif San Diego, Dept Chem & Biochem, La Jolla, CA 92093 USA

来源：

DALTON TRANSACTIONS | 2012年 / 41卷 / 20期

基金：

美国国家科学基金会;

关键词：

POSTSYNTHETIC MODIFICATION; METHANE ADSORPTION; SIMULATIONS; AREA; MOFS;

D O I：

10.1039/c2dt30120b

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A series of highly porous University of Michigan Crystalline Material (UMCM-1) type Zn-based metal-organic frameworks (MOFs) were synthesized from mono-and bi-functionalized benzenedicarboxylate (BDC) ligands. In total, 16 new functionalized UMCM-1 derivatives were obtained by a combination of pre- and postsynthetic functionalization. Through postsynthetic modification (PSM), amino-halo bifunctional MOFs were converted into amide-halo materials via solid-state acylation reactions. A series of bifunctional MOFs containing Cl, Br, and I groups revealed that PSM conversion is not affected by the size of the halide, only by the steric bulk of the reagent used in these solid-state organic transformations.

引用

页码：6277 / 6282

页数：6

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