Infrared absorption spectra of molecular crystals: Possible evidence for small-polaron formation?

被引：12

作者：

Przulj, Zeljko ^{[1
]}

Cevizovic, Dalibor ^{[1
]}

Zekovic, Slobodan ^{[1
]}

Ivic, Zoran ^{[1
]}

机构：

[1] Vinca Inst Nucl Sci, Lab Theoret & Condensed Matter Phys 020, Belgrade 11001, Serbia

来源：

CHEMICAL PHYSICS LETTERS | 2008年 / 462卷 / 4-6期

关键词：

D O I：

10.1016/j.cplett.2008.07.081

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The temperature dependence of the position of the so-called anomalous band peaked at 1650 cm(-1) in the IR-absorption spectrum of crystalline acetanilide (ACN) is theoretically investigated within the small-polaron theory. Its pronounced shift towards the position of the normal band is predicted with the rise of temperature. Interpretation of the IR-absorption spectra in terms of small-polaron model has been critically assessed on the basis of these results. (c) 2008 Elsevier B. V. All rights reserved.

引用

页码：213 / 216

页数：4

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