Cycleable graphite/FeSi6 alloy composite as a high capacity anode material for Li-ion batteries

被引：65
|
作者：
Li, T. [1 ]
Cao, Y. L. [1 ]
Ai, X. P. [1 ]
Yang, H. X. [1 ]
机构：
[1] Wuhan Univ, Dept Chem, Wuhan 430072, Peoples R China
来源：
JOURNAL OF POWER SOURCES | 2008年 / 184卷 / 02期
关键词：
Fe-Si alloy; Mechanical ball milling; Anode material; Li-ion battery;
D O I：
10.1016/j.jpowsour.2008.02.057
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
FeSi6/graphite composite was prepared by mechanical ball milling. The FeSi6 alloy particles consist of an electrochemically active silicon phase and inactive phases FeSi2, distributed uniformly in the graphite matrix. The composite anode offers a large reversible capacity (about 800 mAh g(-1)) and good cycleability. due to the buffering effect of the inactive FeSi2 phase and graphite layers on the volumetric changes of Si phase during lithium-Si alloying reaction. Since FeSi6 alloy is a low-cost industrial material, this alloy compound provides a possible alternative for development of high capacity lithium-ion batteries. (c) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码：473 / 476
页数：4
相关论文
共 50 条
  • [21] Germanium tin alloy nanowires as anode materials for high performance Li-ion batteries
    Doherty, Jessica
    McNulty, David
    Biswas, Subhajit
    Moore, Kalani
    Conroy, Michele
    Bangert, Ursel
    O'Dwyer, Colm
    Holmes, Justin D.
    NANOTECHNOLOGY, 2020, 31 (16)
  • [22] Sol-gel derived nano-crystalline CaSnO3 as high capacity anode material for Li-ion batteries
    Sharma, N
    Shaju, KM
    Rao, GVS
    Chowdari, BVR
    ELECTROCHEMISTRY COMMUNICATIONS, 2002, 4 (12) : 947 - 952
  • [23] Hollow reduced graphene oxide microspheres as a high-performance anode material for Li-ion batteries
    Mei, Riguo
    Song, Xiaorui
    Hu, Yan
    Yang, Yanfeng
    Zhang, Jingjie
    ELECTROCHIMICA ACTA, 2015, 153 : 540 - 545
  • [24] Study of nano-porous Si/Graphite/C composite anode materials for Li-ion batteries
    Zheng Ying
    Yang Jun
    Tao Liang
    Nuli Yan-Na
    Wang Jiu-Lin
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2007, 23 (11) : 1882 - 1886
  • [25] Intercalated SiOC/graphene composites as anode material for li-ion batteries
    Ren, YuRong
    Yang, Bo
    Huang, XiaoBing
    Chu, FuQiang
    Qiu, Jianhua
    Ding, JianNing
    SOLID STATE IONICS, 2015, 278 : 198 - 202
  • [26] Evaluation on a water-based binder for the graphite anode of Li-ion batteries
    Zhang, SS
    Xu, K
    Jow, TR
    JOURNAL OF POWER SOURCES, 2004, 138 (1-2) : 226 - 231
  • [27] TIN-ANTIMONY OXIDE-GRAPHITE COMPOSITE AS ANODE MATERIAL WITH HIGH CAPACITY FOR LITHIUM-ION BATTERIES
    Tang, Liangpeng
    Wei, Ran
    Xie, Wenqing
    Liu, Xiaoqing
    Shang, Chen
    Zhang, Junjie
    SURFACE REVIEW AND LETTERS, 2024,
  • [28] Silicon nitride as anode material for Li-ion batteries: Understanding the SiNx conversion reaction
    Ulvestad, Asbjorn
    Mxhlen, Jan Petter
    Kirkengen, Martin
    JOURNAL OF POWER SOURCES, 2018, 399 : 414 - 421
  • [29] Graphite-Aluminium Composite Anode for Li-Ion Battery by High Energy Ball Milling
    Naidu, J. S.
    Srinivas, M.
    Sujatha, V.
    TRANSACTIONS OF THE INDIAN INSTITUTE OF METALS, 2017, 70 (10) : 2661 - 2666
  • [30] Revisit of Polyaniline as a High-Capacity Organic Cathode Material for Li-Ion Batteries
    Zhao, Ruirui
    Chang, Zu
    Fu, Xudong
    Xu, Mingli
    Ai, Xinping
    Qian, Jiangfeng
    POLYMERS, 2024, 16 (10)
12345