Mechanical Properties and UV Curing Behavior of Poly(N-Isopropylacrylamide) in Phosphonium-Based Ionic Liquids

被引：13

作者：

Ziolkowski, Bartosz ^{[1
]}

Ates, Zeliha ^{[2
]}

Gallagher, Simon ^{[1
]}

Byrne, Robert ^{[1
]}

Heise, Andreas ^{[2
]}

Fraser, Kevin J. ^{[1
]}

Diamond, Dermot ^{[1
]}

机构：

[1] Dublin City Univ, Sch Chem Sci, Natl Ctr Sensor Res, Ctr Sensor Web Technol,Clarity, Dublin 9, Ireland

[2] Dublin City Univ, Sch Chem Sci, Dublin 9, Ireland

来源：

MACROMOLECULAR CHEMISTRY AND PHYSICS | 2013年 / 214卷 / 07期

基金：

爱尔兰科学基金会;

关键词：

ionic liquids; ionogels; N-isopropylacrylamide (NIPAM); viscoelastic properties; RADICAL POLYMERIZATION; ELECTROLYTES; KINETICS; LI; MICROVALVES; MICROPUMPS; POLYMERS; MONOMERS; PNIPAM; SALTS;

D O I：

10.1002/macp.201200616

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

N-isopropylacrylamide (NIPAM) is photopolymerized in a range of phosphonium-based ionic liquids (ILs). The curing behaviour of polymer-IL solutions (linear pNIPAM) and ionogels (crosslinked pNIPAM) is studied using rheometry, DSC, and GPC. It is found that the IL influences the mechanical properties, the rate of polymerization, and the LCST of the resulting pNIPAM ionogels. Ionogels made in trihexyl-tetradecyl phosphonium dicyanamide show an order of magnitude smaller ratio of loss/storage moduli compared to that of trihexyl-tetradecyl phosphonium chloride, and a doubling of the UV polymerization rate. Temperature-ramp rheology scans of the water-swollen ionogels show that upon LCST transition the moduli of the polymer network exhibit anion dependent increases.

引用

页码：787 / 796

页数：10

共 65 条

[1] Understanding the polarity of ionic liquids [J].

Ab Rani, M. A. ;

Brant, A. ;

Crowhurst, L. ;

Dolan, A. ;

Lui, M. ;

Hassan, N. H. ;

Hallett, J. P. ;

Hunt, P. A. ;

Niedermeyer, H. ;

Perez-Arlandis, J. M. ;

Schrems, M. ;

Welton, T. ;

Wilding, R. .

PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2011, 13 (37) :16831-16840

[2] Kinetics of the benzoyl peroxide/amine initiated free-radical polymerization of dental dimethacrylate monomers: Experimental studies and mathematical modeling for TEGDMA and bis-EMA [J].

Achilias, DS ;

Sideridou, ID .

MACROMOLECULES, 2004, 37 (11) :4254-4265

[3] Stimuli responsive polymers for biomedical applications [J].

Alarcón, CDH ;

Pennadam, S ;

Alexander, C .

CHEMICAL SOCIETY REVIEWS, 2005, 34 (03) :276-285

[4] Photopolymerization kinetics of multifunctional monomers [J].

Andrzejewska, E .

PROGRESS IN POLYMER SCIENCE, 2001, 26 (04) :605-665

[5] Photoinitiated polymerization in ionic liquids: Kinetics and viscosity effects [J].

Andrzejewska, Ewa ;

Podgorska-Golubska, Malgorzata ;

Stepniak, Izabela ;

Andrzejewski, Madej .

POLYMER, 2009, 50 (09) :2040-2047

[6] Microvalves and Micropumps for BioMEMS [J].

Au, Anthony K. ;

Lai, Hoyin ;

Utela, Ben R. ;

Folch, Albert .

MICROMACHINES, 2011, 2 (02) :179-220

[7] Conductivities and transport properties of gelled electrolytes with and without an ionic liquid for Li and Li-ion batteries [J].

Bansal, D ;

Cassel, F ;

Croce, F ;

Hendrickson, M ;

Plichta, E ;

Salomon, M .

JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (10) :4492-4496

[8] Ionogel-based light-actuated valves for controlling liquid flow in micro-fluidic manifolds [J].

Benito-Lopez, Fernando ;

Byrne, Robert ;

Raduta, Ana Maria ;

Vrana, Nihal Engin ;

McGuinness, Garrett ;

Diamond, Dermot .

LAB ON A CHIP, 2010, 10 (02) :195-201

[9] Industrial preparation of phosphonium ionic liquids [J].

Bradaric, CJ ;

Downard, A ;

Kennedy, C ;

Robertson, AJ ;

Zhou, YH .

GREEN CHEMISTRY, 2003, 5 (02) :143-152

[10] Characterisation and analytical potential of a photo-responsive polymeric material based on spiropyran [J].

Byrne, Robert ;

Ventura, Claudia ;

Lopez, Fernando Benito ;

Walther, Adelheid ;

Heise, Andreas ;

Diamond, Dermot .

BIOSENSORS & BIOELECTRONICS, 2010, 26 (04) :1392-1398

← 1 2 3 4 5 6 7 →