Multifunctional Supramolecular Hybrid Materials Constructed from Hierarchical Self-Ordering of In Situ Generated Metal-Organic Framework (MOF) Nanoparticles

被引：109
作者：
Chaudhari, Abhijeet K. [1 ]
Han, Intaek [2 ]
Tan, Jin-Chong [1 ]
机构：
[1] Univ Oxford, Dept Engn Sci, Oxford OX1 3PJ, England
[2] Samsung Elect, Samsung Adv Inst Technol, Mat Res Ctr, Suwon 443803, South Korea
来源：
ADVANCED MATERIALS | 2015年 / 27卷 / 30期
基金：
英国工程与自然科学研究理事会;
关键词：
hierarchical self-assembly; metal-organic frameworks; sol-gel; stimuli-responsive materials; supramolecular materials; ELECTRICAL-CONDUCTIVITY; CRYSTAL-GROWTH; POLYMER; GEL; HKUST-1; CHEMISTRY; COATINGS; ACID;
D O I：
10.1002/adma.201501448
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A synergistic approach is described to engineer supramolecular hybrid materials based on metal-organic frameworks, encompassing HKUST-1 nanoparticles formed in situ, coexisting with an electrically conducting gel fiber network. The following findings are made: i) multistimuli-responsive structural transformation via reversible sol-gel switching and ii) radical conversion of a soft hybrid gel into a mechanically malleable, viscoelastic matter.
引用
收藏
页码：4438 / 4446
页数：9
相关论文
共 55 条
[1]   Functional Supramolecular Polymers [J].
Aida, T. ;
Meijer, E. W. ;
Stupp, S. I. .
SCIENCE, 2012, 335 (6070) :813-817
[2]   Exploration of Chemically Cross-Linked Metal-Organic Frameworks [J].
Allen, C. A. ;
Cohen, S. M. .
INORGANIC CHEMISTRY, 2014, 53 (13) :7014-7019
[3]  
Ameloot R, 2011, NAT CHEM, V3, P382, DOI [10.1038/NCHEM.1026, 10.1038/nchem.1026]
[4]   Thixotropy - A review [J].
Barnes, HA .
JOURNAL OF NON-NEWTONIAN FLUID MECHANICS, 1997, 70 (1-2) :1-33
[5]   Thermochemistry of Paddle Wheel MOFs: Cu-HKUST-1 and Zn-HKUST-1 [J].
Bhunia, Manas K. ;
Hughes, James T. ;
Fettinger, James C. ;
Navrotsky, Alexandra .
LANGMUIR, 2013, 29 (25) :8140-8145
[6]  
Carné-Sánchez A, 2013, NAT CHEM, V5, P203, DOI [10.1038/NCHEM.1569, 10.1038/nchem.1569]
[7]  
Chaudhuri P, 1999, ANGEW CHEM INT EDIT, V38, P1095, DOI 10.1002/(SICI)1521-3773(19990419)38:8<1095::AID-ANIE1095>3.0.CO
[8]  
2-I
[9]  
Chaudhuri P., 1998, Angew. Chem, V110, P2340, DOI DOI 10.1002/(SICI)1521-3757(19980817)110:16<2340::AID-ANGE2340>3.0.CO
[10]  
2-C
123456