New Concepts in Electrolytes

被引:752
作者
Li, Matthew [2 ,3 ]
Wang, Chunsheng [4 ]
Chen, Zhongwei [3 ]
Xu, Kang [1 ]
Lu, Jun [2 ]
机构
[1] US Army, Energy Storage Branch, Sensor & Electron Directorate, Res Lab, Adelphi, MD 20783 USA
[2] Argonne Natl Lab, Chem Sci & Engn Div, Lemont, IL 60439 USA
[3] Univ Waterloo, Waterloo Inst Nanotechnol, Dept Chem Engn, Waterloo, ON N2L 3G1, Canada
[4] Univ Maryland, Dept Chem & Biomol Engn, Dept Chem & Biochem, College Pk, MD 20742 USA
基金
加拿大自然科学与工程研究理事会;
关键词
LITHIUM-METAL BATTERIES; REDOX-FLOW BATTERY; LI-ION BATTERY; NANOPARTICLE HYBRID ELECTROLYTES; IN-SALT ELECTROLYTE; HIGH-ENERGY DENSITY; SOLID-ELECTROLYTE; POLYMER ELECTROLYTES; SUPERCONCENTRATED ELECTROLYTES; PHYSICOCHEMICAL PROPERTIES;
D O I
10.1021/acs.chemrev.9b00531
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Over the past decades, Li-ion battery (LIB) has turned into one of the most important advances in the history of technology due to its extensive and in-depth impact on our life. Its omnipresence in all electric vehicles, consumer electronics and electric grids relies on the precisely tuned electrochemical dynamics and interactions among the electrolytes and the diversified anode and cathode chemistries therein. With consumers' demand for battery performance ever increasing, more and more stringent requirements are being imposed upon the established equilibria among these LIB components, and it became clear that the state-of-the-art electrolyte systems could no longer sustain the desired technological trajectory. Driven by such gap, researchers started to explore more unconventional electrolyte systems. From superconcentrated solvent-in-salt electrolytes to solid-state electrolytes, the current research realm of novel electrolyte systems has grown to unprecedented levels. In this review, we will avoid discussions on current state-of-the-art electrolytes but instead focus exclusively on unconventional electrolyte systems that represent new concepts.
引用
收藏
页码:6783 / 6819
页数:37
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