Synthesis, characterization of a new tamarind based ion exchange resin and use for the separation of heavy metal ions in industrial wastewater

被引：0

作者：

Singh, A. V. ^{[1
]}

Kumawat, Indraj Kumar ^{[1
]}

机构：

[1] Jai Narain Vyas Univ, Dept Chem, Jodhpur 342033, Rajasthan, India

来源：

JOURNAL OF THE INDIAN CHEMICAL SOCIETY | 2012年 / 89卷 / 09期

关键词：

Ion exchange capacity; TNDSA resin; batch method; distribution coefficient; heavy metal ions; ACTIVATED CARBON; CATION-EXCHANGER; CHELATING RESIN; REMOVAL; ADSORPTION; EFFLUENT; SORPTION; COPPER; POLYSACCHARIDE; EXTRACTION;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new tamarind kernel powder based resin containing 1-napthol-3,6-disulphonic acid group has been synthesized by modified Porath's method of functionalisation of polysaccharides. Resin synthesized from TKP possesses an excellent ion-exchange property due to high selectivity for metal ions. The resin was characterized on the basis of chemical composition, Fourier-transform infrared spectroscopy, ion-exchange capacity, thermogravimetric analysis and physicochemical properties. The distribution coefficient (K-d) values and influence of pH on chelation of these metal ions were studied using batch method. The separations of mixture of Fe-II, Cu-II, Zn-II, Cd-II and Pb-II metal ions on TNDSA resin on the basis of their distribution coefficient at various pH were also achieved using column chromatograph. The effects of experimental parameters such as pH, treatment time, temperature and resin dose on the removal of metal ions have been also studied. These results show that TNDSA resin hold great potential to remove heavy metal species from industrial wastewater.

引用

页码：1301 / 1308

页数：8

共 52 条

[1] Heavy metal removal from copper smelting effluent using electrochemical cylindrical flow reactor [J].

Basha, C. Ahmed ;

Bhadrinarayana, N. S. ;

Anantharaman, N. ;

Begum, K. M. Meera Sheriffa .

JOURNAL OF HAZARDOUS MATERIALS, 2008, 152 (01) :71-78

[2] Use of an o-aminobenzoic acid-functionalized XAD-4 copolymer resin for the separation and preconcentration of heavy metal(II) ions [J].

Çekiç, SD ;

Filik, H ;

Apak, R .

ANALYTICA CHIMICA ACTA, 2004, 505 (01) :15-24

[3] Efficiency and application of poly(acryldinitrophenylamidrazone-dinitroacrylphenylhydrazine) chelating fiber for pre-concentrating and separating trace Au(III), Ru(III), In(III), Bi(III), Zr(IV), V(V), Ga(III) and Ti(IV) from solution samples [J].

Chang, XJ ;

Su, QQ ;

Liang, DY ;

Wei, XJ ;

Wang, BT .

TALANTA, 2002, 57 (02) :253-261

[4] Recovery of Cu(II) and Cd(II) by a chelating resin containing aspartate groups [J].

Chen, Chuh-Yean ;

Lin, Mao-Syong ;

Hsu, Kun-Rong .

JOURNAL OF HAZARDOUS MATERIALS, 2008, 152 (03) :986-993

[5] Recent developments in polysaccharide-based materials used as adsorbents in wastewater treatment [J].

Crini, G .

PROGRESS IN POLYMER SCIENCE, 2005, 30 (01) :38-70

[6] Removal of heavy metals from wastewaters by aluminosilicate [J].

de Aguiar, MRMP ;

Novaes, AC ;

Guarino, AWS .

QUIMICA NOVA, 2002, 25 (6B) :1145-1154

[7] Preparation, characterization and sorption properties of crosslinked starch-based exchangers [J].

Delval, F ;

Crini, G ;

Bertini, S ;

Filiatre, C ;

Torri, G .

CARBOHYDRATE POLYMERS, 2005, 60 (01) :67-75

[8] Adsorption of Cu(II), Zn(II), Ni(II), Pb(II), and Cd(II) from aqueous solution on amberlite IR-120 synthetic resin [J].

Demirbas, A ;

Pehlivan, E ;

Gode, F ;

Altun, T ;

Arslan, G .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2005, 282 (01) :20-25

[9] Synthesis and analytical properties of a chelating resin functionalised with bis-(N,N'-salicylidene)1,3-propanediamine ligands [J].

Dev, K ;

Rao, GN .

TALANTA, 1996, 43 (03) :451-457

[10]

El-Menshawy AM, 2008, CAN J ANAL SCI SPECT, V53, P206

← 1 2 3 4 5 6 →