The effect of acrylamides copolymers on the stability and rheological properties of yellow iron oxide dispersion

被引:10
作者
Liang, Caizhen [1 ,2 ]
Wang, Bin [1 ]
Chen, Jianjun [1 ,2 ]
Huang, Yuewen [1 ]
Fang, Tianyong [1 ,2 ]
Wang, Yingying [1 ,2 ]
Liao, Bing [3 ]
机构
[1] Chinese Acad Sci, Guangzhou Inst Chem, Key Lab Cellulose & Lignocellulos Chem, Guangzhou 510650, Guangdong, Peoples R China
[2] Univ Chinese Acad Sci, Beijing 100039, Peoples R China
[3] Guangdong Acad Sci, Guangzhou 510650, Guangdong, Peoples R China
关键词
Yellow iron oxide; PMBAs; Rheological property; Stability; Low viscosity; Dispersion ability; RAFT POLYMERIZATION; COMB-LIKE; SUSPENSIONS; STABILIZATION; NANOPARTICLES; VISCOSITY; TIO2; ADSORPTION; NANOFLUIDS; HYDROXIDE;
D O I
10.1016/j.colsurfa.2016.10.020
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
It is still a challenge to disperse yellow iron oxides in organic media due to their susceptible aggregation, which limits their application in ceramic material area. In order to achieve colloidal stabilization in organic liquid, yellow iron oxides were dispersed in ethanol with p[methyl methacrylate-r-butyl methacrylate-r-N-(3-dimethylaminopropyl) methacrylamide] random copolymers (PMBAs) based on amino groups as anchoring groups and alkyl as solvent chains by reversible-addition fragmentation chain-transfer radical (RAFT) polymerization. The effect of PMBAs on viscosity, rheological properties and dispersion stability was investigated. In the presence of PMBAs, yellow iron oxide dispersion performed excellent colloidal stability and low viscosity with high solid loadings. Furthermore, it is suggested that PMBAs have outstanding dispersion ability, retarding yellow iron oxides aggregating and keeping it stable for more than 60 days at ambient temperature. This study reveals that PMBAs might find promising application in material dispersion area. (C) 2016 Published by Elsevier B.V.
引用
收藏
页码:136 / 145
页数:10
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