Kinetics and mechanism of liquid-phase thermal decomposition of β-cyanoethyl-N-nitramines

被引：3

作者：

Stepanov, RS ^{[1
]}

Astakhov, AM ^{[1
]}

Kruglyakova, LA ^{[1
]}

Pekhotin, KV ^{[1
]}

机构：

[1] Siberian State Technol Univ, Kranoyarsk, Russia

来源：

RUSSIAN JOURNAL OF GENERAL CHEMISTRY | 2002年 / 72卷 / 08期

关键词：

Oxide; Nitrogen; Thermal Decomposition; Nitrogen Atom; Similar Condition;

D O I：

10.1023/A:1020888031524

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Termal decomposition of beta-cyanoethyl-N-nitraniine in melt is preceded by protonation of the amino nitrogen atom and is accompanied by evolution of nitrogen(1) oxide with formation of acrylonitrile. Thermal decomposition of bis(beta-cyanoethyl)-N-nitramine under similar conditions follows a radical mechanism with initial dissociation of the N-N bond. The same mechanism is operative in thermal decomposition of both N-nitramines in a dilute dibutyl phthalate solution.

引用

页码：1256 / 1258

页数：3

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