Synthesis, structure and catalytic activities for the hydrogen transfer reactions of the ruthenium(II) carbonyl chloride complexes with pyridine-2,6-diimine

被引：17

作者：

Lu, Xiang-Yong ^{[1
]}

Xu, Hui-Jun ^{[1
]}

Chen, Xue-Tai ^{[1
]}

机构：

[1] Nanjing Univ, Sch Chem & Chem Engn, Nanjing Natl Lab Microstruct, State Key Lab Coordinat Chem, Nanjing 210093, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2009年 / 12卷 / 09期

关键词：

Ruthenium complex; Crystal structure; Transfer hydrogenation; Pyridine-2,6-diimine; LIGANDS; MONONUCLEAR; KETONES; BONDS; RINGS; CHAIN;

D O I：

10.1016/j.inoche.2009.07.004

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two Ru(II) carbonyl chloride complexes with pyridine-2,6-diimine, (L)Ru(CO)Cl-2 (L = 2,6-diacetylpyri-dinebis(2,4,6-trimethylanil), 1: L = 2,6-diacetylpyridinebis(2,6-diisopropylanil), 2) have been synthesized and characterized. The structure of compound I has been determined by X-ray crystallography, which show the distorted octahedral geometry around Ru(II). Complexes 1 and 2 have been proved to be active in the transfer hydrogenation of acetophenone by propan-2-ol. (C) 2009 Elsevier B.V. All rights reserved.

引用

页码：887 / 889

页数：3

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