Liquid-Liquid Phase Transition in Supercooled Yttria-Alumina

被引:53
|
作者
Barnes, Adrian C. [1 ]
Skinner, Lawrie B. [1 ]
Salmon, Philip S. [2 ]
Bytchkov, Alexei [3 ]
Pozdnyakova, Irina [4 ]
Farmer, Thomas O. [1 ]
Fischer, Henry E. [5 ]
机构
[1] Univ Bristol, HH Wills Phys Lab, Bristol BS8 1TL, Avon, England
[2] Univ Bath, Dept Phys, Bath BA2 7AY, Avon, England
[3] European Synchrotron Radiat Facil, F-38043 Grenoble, France
[4] Univ Orleans, CNRS, CEMHTI, F-45071 Orleans 2, France
[5] Inst Max Von Laue Paul Langevin, F-38042 Grenoble, France
基金
英国工程与自然科学研究理事会;
关键词
PHOSPHORUS; SEPARATION; AL2O3-Y2O3; GLASSES; DENSITY; SYSTEM; WATER;
D O I
10.1103/PhysRevLett.103.225702
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
The structure and thermal characteristics of aerodynamically levitated samples of yttria-alumina in the liquid, supercooled liquid and solid phases were explored in an extensive series of high energy x-ray diffraction, small angle neutron scattering, and pyrometric cooling measurements. Particular focus was placed on the compound (Y(2)O(3))(x)(Al(2)O(3))(1-x) with x=0.2 for which a liquid-liquid phase transition at a temperature of 1788 K has recently been reported. No structural or thermal signature in support of this metastable phase transition could be found.
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页数:4
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