Hydrophilic NiFe-LDH/Ti3C2Tx/NF electrode for assisting efficiently oxygen evolution reaction

被引:13
作者
Si, Huizheng [1 ,2 ]
Han, Chong [1 ,2 ]
Cui, Yangbo [1 ,2 ]
Sang, Shangbin [1 ]
Liu, Kaiyu [1 ]
Liu, Hongtao [1 ]
Wu, Qiumei [2 ]
机构
[1] Cent South Univ, Hunan Prov Key Lab Chem Power Sources, Coll Chem & Chem Engn, Changsha 410083, Peoples R China
[2] Cent South Univ, State Key Powder Met Lab, Changsha 410083, Peoples R China
关键词
Ti3C2Tx; Interface; NiFe-LDH; Electrocatalysts; OER; LAYERED DOUBLE-HYDROXIDE; NICKEL FOAM; NANOTUBE ARRAYS; ELECTROCATALYST; MXENE; NANOPARTICLES; PERFORMANCE; NANOSHEETS; CATALYST; GROWTH;
D O I
10.1016/j.jssc.2020.121943
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Electrolytic water splitting, consists of hydrogen evolution reaction (HER) and oxygen evolution reaction (OER), still has many challenges because of the high cost and scarify of the indispensable noble metal catalysts. Herein, the costless and effective NiFe layered double hydroxide (NiFe-LDH), supported on the Ti3C2Tx modified 3D nickel foam (NF), is used instead of noble metal to intensify the transfer ability of the charges as well as ions in the OER catalysis process. The prepared NiFe-LDH/Ti3C2Tx/NF electrode has a lower overpotential (240 mV at 50 mA cm(-2)) and Tafel slope (82 mV dec(-1)) as compared with that of IrO2/Ti3C2Tx/NF(400 mV, 252 mV dec(-1)). Meanwhile, it has a good endurance and stability with a negligible voltage changing after 15 h of testing. The work provides reference for the synthetic of catalyst with high catalytic kinetics and activity in the field of electrolytic water splitting.
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页数:8
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