Surface chemistry in three dimensions: CO dissociation between two surfaces

被引：4
|
作者：
Bollinger, MV [1 ]
Jacobsen, KW [1 ]
Norskov, JK [1 ]
机构：
[1] Tech Univ Denmark, Dept Phys, Ctr Atom Scale Mat Phys, DK-2800 Lyngby, Denmark
来源：
CHEMICAL PHYSICS LETTERS | 2000年 / 322卷 / 05期
关键词：
D O I：
10.1016/S0009-2614(00)00439-5
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Based on self-consistent density functional calculations it is shown that a new dissociation process for CO adsorbed on a Ru(0001) surface is made possible when the distance to a second Ru(0001) surface placed just above it is below some critical value. This '3D' process is more facile than the usual single surface ('2D') process because indirect adsorbate-adsorbate interactions in the transition state are absent in the '3D' case. The prospects for STM-induced single molecule chemistry and for '3D' catalysts are discussed. (C) 2000 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：307 / 311
页数：5
相关论文
共 50 条
  • [41] Airway volume analysis: is there a correlation between two and three-dimensions?
    Martins, Luize Severo
    Liedke, Gabriela Salatino
    Dias da-Silveira, Heraldo Luis
    da Silveira, Priscila Fernanda
    Arus, Nadia Assein
    Ongkosuwito, Edwin M.
    Vizzotto, Mariana Boessio
    EUROPEAN JOURNAL OF ORTHODONTICS, 2018, 40 (03) : 262 - 267
  • [42] Contraction of excess fibres between the Mckay correspondences in dimensions two and three
    Boissiere, Samuel
    Sarti, Alessandra
    ANNALES DE L INSTITUT FOURIER, 2007, 57 (06) : 1839 - 1861
  • [43] Structure Sensitivity of CO Dissociation on Rh Surfaces
    M. Mavrikakis
    M. Bäumer
    H.-J. Freund
    J.K. Nørskov
    Catalysis Letters, 2002, 81 : 153 - 156
  • [44] THE DISSOCIATION OF CO ON MODIFIED MO(110) SURFACES
    ERICKSON, JW
    ESTRUP, PJ
    SURFACE SCIENCE, 1986, 167 (2-3) : 519 - 533
  • [45] CHEMISTRY IN NONINTEGER DIMENSIONS BETWEEN 2 AND 3 .1. FRACTAL THEORY OF HETEROGENEOUS SURFACES
    PFEIFER, P
    AVNIR, D
    JOURNAL OF CHEMICAL PHYSICS, 1983, 79 (07): : 3558 - 3565
  • [46] Structure sensitivity of CO dissociation on Rh surfaces
    Mavrikakis, M
    Bäumer, M
    Freund, HJ
    Norskov, JK
    CATALYSIS LETTERS, 2002, 81 (3-4) : 153 - 156
  • [47] STUDY OF CO DESORPTION AND DISSOCIATION ON RH SURFACES
    NEHASIL, V
    STARA, I
    MATOLIN, V
    SURFACE SCIENCE, 1995, 331 : 105 - 109
  • [48] Semilandmarks on curves and surfaces in three dimensions.
    Mitteroeeker, P
    Gunz, P
    AMERICAN JOURNAL OF PHYSICAL ANTHROPOLOGY, 2002, : 114 - 115
  • [49] STATIC GRASP STABILITY OF TWO OBJECTS APPROXIMATED WITH ELLIPSOIDAL SURFACE IN THREE DIMENSIONS
    Yamada, Takayoshi
    Funahashi, Yasuyuki
    Yamamoto, Hidehiko
    EMERGING TRENDS IN MOBILE ROBOTICS, 2010, : 288 - 295
  • [50] Surface chemistry - Reactions on semiconductor surfaces
    Ruda, HE
    SCIENCE, 1999, 283 (5402) : 646 - 647
12345