Synergistic Effects of ppm Levels of Palladium on Natural Clinochlore for Reduction of Nitroarenes

被引：21

作者：

Gholinejad, Mohammad ^{[1
,2
]}

Oftadeh, Erfan ^{[1
]}

Shojafar, Mohammad ^{[1
]}

Sansano, Jose M. ^{[3
,4
]}

Lipshutz, Bruce H. ^{[5
]}

机构：

[1] Inst Adv Studies Basic Sci, Dept Chem, POB 45195-1159, Gavazang 4513766731, Zanjan, Iran

[2] Inst Adv Studies Basic Sci, Res Ctr Basic Sci & Modern Technol, Zanjan 4513766731, Iran

[3] Univ Alicante, Inst Sintesis Organ, Dept Quim Organ, Apdo 99, E-03080 Alicante, Spain

[4] Univ Alicante, Ctr Innovac Quim Avanzada ORFEO CINQA, Apdo 99, E-03080 Alicante, Spain

[5] Univ Calif Santa Barbara, Dept Chem & Biochem, Santa Barbara, CA 93106 USA

来源：

CHEMSUSCHEM | 2019年 / 12卷 / 18期

基金：

美国国家科学基金会;

关键词：

clay; nitro compounds; palladium; reduction; synergistic effects; AROMATIC NITRO-COMPOUNDS; HETEROGENEOUS CATALYSIS; SELECTIVE REDUCTION; EFFICIENT; NANOCATALYSTS; NANOPARTICLES; WATER; NITROAROMATICS; COUPLINGS; AMINES;

D O I：

10.1002/cssc.201901535

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Augmenting the modified naturally occurring clay clinochlore with ppm amounts of palladium leads to a new and very effective reagent for the reduction of numerous aromatic nitro species. When palladium nanoparticles are supported on pyridyltriazole-modified clinochlore, iron within clinochlore acts synergistically with palladium to catalyze the reduction of a wide variety of nitroarenes at room temperature in aqueous media. Based on E-factor calculations, the catalyst system is found to be in line with green chemistry standards and can be recycled up to five times.

引用

页码：4240 / 4248

页数：9

共 50 条

[21] Palladium Supported on Graphitic Carbon Nitride: An Efficient and Recyclable Heterogeneous Catalyst for Reduction of Nitroarenes and Suzuki Coupling Reaction
Zhao, Yukai
Tang, Ruiren
Huang, Rong
CATALYSIS LETTERS, 2015, 145 (11) : 1961 - 1971
[22] Chemoselective reduction of nitroarenes, N-acetylation of arylamines, and one-pot reductive acetylation of nitroarenes using carbon-supported palladium catalytic system in water
Zeynizadeh, Behzad
Mohammad Aminzadeh, Farkhondeh
Mousavi, Hossein
RESEARCH ON CHEMICAL INTERMEDIATES, 2021, 47 (08) : 3289 - 3312
[23] Gold nanoparticles supported on NiO and CuO: The synergistic effect toward enhanced reduction of nitroarenes and A3-coupling reaction
Gholinejad, Mohammad
Khezri, Rahimeh
Nayeri, Sara
Vishnuraj, Ramakrishnan
Pullithadathil, Biji
MOLECULAR CATALYSIS, 2022, 530
[24] Nitrogen-enriched carbon nanotube supported palladium as a catalyst for desulfurization of dibenzothiophene and reduction of nitroarenes
Gholinejad, Mohammad
Elkhani, Zeynab
Nayeri, Sara
Sansano, Jose M.
SCIENTIFIC REPORTS, 2025, 15 (01):
[25] Aminal-based Hypercrosslinked Polymer Modified with Small Palladium Nanoparticles for Efficiently Catalytic Reduction of Nitroarenes
Xu, Dan
Wang, Fushan
Yu, Guiqin
Zhao, Hong
Yang, Jing
Yuan, Man
Zhang, Xiaoyun
Dong, Zhengping
CHEMCATCHEM, 2018, 10 (20) : 4569 - 4577
[26] Mechanistic Study of the Palladium-Phenanthroline Catalyzed Carbonylation of Nitroarenes and Amines: Palladium-Carbonyl Intermediates and Bifunctional Effects
Ragaini, Fabio
Gasperini, Michela
Cenini, Sergio
Arnera, Lucia
Caselli, Alessandro
Macchi, Piero
Casati, Nicola
CHEMISTRY-A EUROPEAN JOURNAL, 2009, 15 (32) : 8064 - 8077
[27] Highly recyclable palladium ion substituted TiO2 as the versatile ligand-free catalyst for the selective oxidation of alcohols and the reduction of nitroarenes
Prasanna
Usha, K. M.
JOURNAL OF CHEMICAL SCIENCES, 2022, 134 (04)
[28] Immobilization of palladium on benzimidazole functionalized mesoporous silica nanoparticles: catalytic efficacy in Suzuki–Miyaura reaction and nitroarenes reduction
Mehrnoosh Jalalzadeh-Esfahani
Tahereh Sedaghat
Azizollah Beheshti
Roya Azadi
Journal of Porous Materials, 2022, 29 : 1149 - 1164
[29] Polymer supported palladium nanocrystals as efficient and recyclable catalyst for the reduction of nitroarenes to anilines under mild conditions in water
Dell'Anna, Maria Michela
Intini, Simona
Romanazzi, Giuseppe
Rizzuti, Antonino
Leonelli, Cristina
Piccinni, Ferruccio
Mastrorilli, Piero
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2014, 395 : 307 - 314
[30] Palladium nanoparticles embedded over chitosan/γMnO2 composite hybrid microspheres as heterogeneous nanocatalyst for effective reduction of nitroarenes and organic dyes in water
Caliskan, Melike
Baran, Talat
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2022, 963

← 1 2 3 4 5 →